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Sintesis nanokomposit natrium alginat-TiO2-bentonite teraktivasi: studi kinetika fotokatalisis dan adsorpsi untuk pengurangan limbah zat warna methylene blue (MB) = Synthesis of nanocomposite sodium alginate TiO2 activated bentonite: kinetics study and isotherm adsorption in degradation process of methylene blue (MB) dyes

Randi Subekti; Helmiyati, supervisor; Ivandini Tribidasari Anggraningrum, examiner; Munawar Khalil, examiner; Rahmat Wibowo, examiner (Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Indonesia, 2018)

 Abstract

Pada penelitian ini nanokomposit Natrium Alginat-Bentonite-TiO2 telah berhasil disitesis. Hasil sintesis yang diperoleh dilakukan karakterisasi menggunakan FTIR, XRD, SEM, EDX dan TEM untuk mengetahui sifat dari nanokomposit yang diperoleh. Nanokomposit yang telah disintesis memiliki bandgap 3.01 eV dengan distribusi ukuran partikel TiO2 kurang dari 500 nm. Nanokomposit diaplikasikan untuk uji adsorpsi dan fotokatalisis dalam pengurangan limbah zat warna Methylene Blue MB . Persen degradasi yang didapat yaitu sebesar 95,01 dalam kondisi optimum pada pH 8, waktu adsorpsi 30 menit dan massa adsorben 30 mg. Isotherm adsorpsi dari proses yang terjadi mengikuti isotherm Langmuir dengan nilai R2 yaitu 0.971. Untuk proses fotokatalisis, telah dipelajari studi kinetika dimana reaksi yang berjalan mengikuti kinetika orde satu dengan nilai R2 yaitu 0.9420 dan konstanta lanju k sebesar 0.008.

In this study, sodium alginate Bentonite TiO2 nanocomposite has been successfully synthesized in this study. The synthesis results obtained were characterized using FTIR, XRD, SEM, EDX and TEM to determine the properties of the acquired nanocomposites. The synthesized nanocomposite has a 3.01 ev bandgap with a particle size distribution of TiO2 less than 500 nm. Nanocomposites were applied for the adsorption and photocatalysis tests in the reduction of methylene blue MB dye waste. The percentage of degradation was 95,01 under optimum pH condition of 8, optimal adsorption time of 30 minutes, and the optimal adsorbent mass of 30 mg. The adsorption isotherm of the process that follows Langmuir isotherm with R2 value is 0.971. For the process of photocatalysis, kinetic studies have been studied in which the reaction follows the first order kinetics with the R2 value of 0.9420 and the rate constant k of 0.008.

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Collection Type : UI - Skripsi Membership
Call Number : S-Pdf
Main entry-Personal name :
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Publishing : Depok: Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Indonesia, 2018
Cataloguing Source LibUI ind rda
Content Type text
Media Type computer
Carrier Type online resource
Physical Description xvi, 75 pages : illustration ; appendix
Concise Text
Holding Institution Universitas Indonesia
Location Perpustakaan UI, Lantai 3
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S-Pdf 14-20-731558332 TERSEDIA
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No review available for this collection: 20475306
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