Artikel Jurnal :: Kembali

Artikel Jurnal :: Kembali

Synthesis of lithium titanate (li4ti5O12) by addition of excess lithium carbonate (li2CO3) in titanium dioxide (tiO2) xerogel

Bambang Priyono, Akhmad Herman Yuwono , Evvy Kartini, Heri Jodi, Johansyah (Faculty of Engineering, Universitas Indonesia, 2016)

 Abstrak

Lithium titanate, Li4Ti5O12 (LTO) is a promising candidate as lithium ion battery anode material. In this investigation, LTO was synthesized by a solid state method using TiO2 xerogel prepared by the sol-gel method and lithium carbonate (Li2CO3). Three variations of Li2CO3 content addition in mol% or Li2CO3 molar excess were fabricated, i.e., 0, 50 and 100%, labelled as sample LTO-1, LTO-2 and LTO-3, respectively. The characterizations were made using XRD, FESEM, and BET testing. These were performed to observe the effect of lithium excess addition on structure, morphology, and surface area of the resulting samples. Results showed that the crystallite size and surface area of each sample was 50.80 nm, 17.86 m2/gr for LTO-1; 53.14 nm, 22.53 m2/gr for LTO-2; and 38.09 nm, 16.80 m2/gr for LTO-3. Furthermore, lithium excess caused the formation of impure compound Li2TiO3, while a very small amount of rutile TiO2 was found in LTO-1. A near-pure crystalline Li4Ti5O12 compound was successfully synthesized using the present method with stoichiometric composition with 0% excess, indicating very little Li+ loss during the sintering process.

 Metadata

Jenis Koleksi : Artikel Jurnal
No. Panggil : UI-IJTECH 7:3 (2016)
Entri utama-Nama orang :
Subjek :
Penerbitan : Depok: Faculty of Engineering, Universitas Indonesia, 2016
Sumber Pengatalogan : LibUI eng rda
ISSN : 20869614
Majalah/Jurnal : International Journal of Technology
Volume : Vol. 7, No. 3, April 2016: Hal. 392-400
Tipe Konten : text
Tipe Media : unmediated
Tipe Carrier : volume
Akses Elektronik : https://doi.org/10.14716/ijtech.v7i3.2890
Institusi Pemilik : Universitas Indonesia
Lokasi : Perpustakaan UI, Lantai 4 R. Koleksi Jurnal
  • Ketersediaan
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No. Panggil No. Barkod Ketersediaan
UI-IJTECH 7:3 (2016) 08-23-83268376 TERSEDIA
Ulasan:
Tidak ada ulasan pada koleksi ini: 9999920521669
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