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"Penelitian ini mengkaji satu karakteristik biodiesel dan campuran biodiesel-solar yakni stabilitas oksidasi, bahan bakar dengan stabilitas oksidasi rendah dapat dengan mudah teroksidasi dengan udara, bila telah rancid atau tengik dapat mengakibatkan korosi dan kerusakan pada injektor, tangki dan elemen mesin lain. Metode 743 Rancimat (modified) round robin test khusus untuk menguji stabilitas oksidasi biodiesel, campuran biodiesel-solar dan solar melalui determinasi waktu induksi/induction time, hasilnya B100-UFO atau biodiesel minyak jelantah murni (Used Frying Oil/UFO) memiliki stabilitas oksidasi 1,6 jam (pada 110oC), B95-UFO 2,95 jam, B90-UFO 3,56 jam, B80-UFO 17,13 jam dan B30-UFO 98,24 jam. Dengan standar minimal stablilitas oksidasi 6 jam (EN 14112), Stabilitas oksidasi yang aman bagi mesin diesel dimulai B80 dan grafik trendline meperlihatkan B85 masih aman di kisaran 10 jam. Adapun kinerja mesin diperoleh hasil dibandingkan dengan solar, minyak jelantah sebagai campuran mengakibatkan kenaikan konsumsi bahan bakar untuk daya yang sama, mengakibatkan penurunan Brake Horse Power/BHP untuk semua campuran. Terdapat keunikan pada B15-UFO dibandingkan campuran biodiesel jelantah-solar yang lain yakni memiliki efisiensi thermal yang naik (0,26%) sedangkan campuran yang lain turun, pada kondisi putaran poros tetap memiliki kenaikan SFC yang paling rendah (2,34%) dan memiliki penurunan BHP yang paling rendah (9,38%).

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This research is studying oxidation stability of biodiesel and biodiesel-petrodiesel blends, fuel with low oxidative stability will be oxidized by atmosphere air easily, rancid fuel is corrosive and will damage the injector, tank and other elements. 743 Rancimat Method (modified) round robin test is only for determining the oxidative stability of biodiesel, biodiesel-petrodiesel and petrodiesel by determining induction time. The result : B100-UFO or the neat Used Frying Oil (UFO) Biodiesel has oxidation stability 1,6 hours (at 110oC), B95-UFO 2,95 hours, B90-UFO 3,56 hours, B80-UFO 17,13 hours and B30-UFO 98,24 hours. the minimum standard of oxidation stability is 6 hours (EN 14112), B80 is safe for diesel engine and graph trendline shows B85 is still safe as around 7 hours. The Diesel engine performance results are : w The Diesel engine performance results are : With petrodiesel as the standard, Used Frying Oil as blender make an increase of fuel consumption for the same power, make a decrease of Brake Horse Power/BHP for all blends. There are some uniqueness of the B15-UFO compared with other UFO biodiesel-petrodiesel such as it has an increase thermal efficiency (0,26%)as the other blends are decrease, at constant rotational speed (rpm) it has the lowest increase of SFC (2,34%) and the lowest decrease of BHP (9,38%). ith petrodiesel as the standard, Used Frying Oil as blender make an increase of fuel consumption for the same power, make a decrease of Brake Horse Power/BHP for all blends. There are some uniqueness of the B15-UFO compared with other UFO biodiesel-petrodiesel such as it has an increase thermal efficiency (0,26%)as the other blends are decrease, at constant rotational speed (rpm) it has the lowest increase of SFC (2,34%) and the lowest decrease of BHP (9,38%).;This research is studying oxidation stability of biodiesel and biodiesel-petrodiesel blends, fuel with low oxidative stability will be oxidized by atmosphere air easily, rancid fuel is corrosive and will damage the injector, tank and other elements. 743 Rancimat Method (modified) round robin test is only for determining the oxidative stability of biodiesel, biodiesel-petrodiesel and petrodiesel by determining induction time. The result : B100-UFO or the neat Used Frying Oil (UFO) Biodiesel has oxidation stability 1,6 hours (at 110oC), B95-UFO 2,95 hours, B90-UFO 3,56 hours, B80-UFO 17,13 hours and B30-UFO 98,24 hours. the minimum standard of oxidation stability is 6 hours (EN 14112), B80 is safe for diesel engine and graph trendline shows B85 is still safe as around 7 hours. The Diesel engine performance results are : w The Diesel engine performance results are : With petrodiesel as the standard, Used Frying Oil as blender make an increase of fuel consumption for the same power, make a decrease of Brake Horse Power/BHP for all blends. There are some uniqueness of the B15-UFO compared with other UFO biodiesel-petrodiesel such as it has an increase thermal efficiency (0,26%)as the other blends are decrease, at constant rotational speed (rpm) it has the lowest increase of SFC (2,34%) and the lowest decrease of BHP (9,38%). ith petrodiesel as the standard, Used Frying Oil as blender make an increase of fuel consumption for the same power, make a decrease of Brake Horse Power/BHP for all blends. There are some uniqueness of the B15-UFO compared with other UFO biodiesel-petrodiesel such as it has an increase thermal efficiency (0,26%)as the other blends are decrease, at constant rotational speed (rpm) it has the lowest increase of SFC (2,34%) and the lowest decrease of BHP (9,38%)."

"Penggunaan biodiesel di Indonesia saat ini belum sepenuhnya dijalankan karena biodiesel mudah teroksidasi. Salah satu cara untuk mengatasi masalah oksidasi biodiesel adalah dengan penambahan antioksidan. Pyrogallol adalah antioksidan yang umum digunakan, tetapi pyrogallol dan biodiesel memiliki polaritas yang berbeda sehingga menyebabkan keduanya tidak terdistribusi dengan baik. Perlu dilakukan peningkatan distribusi pyrogallol di dalam biodiesel dengan penambahan surfaktan. Surfaktan adalah senyawa yang digunakan untuk meningkatkan dispersi antara dua senyawa yang tidak saling larut. Glycerol monostearate adalah surfaktan yang umum digunakan untuk mencampurkan bahan aditif yang bersifat polar pada minyak nabati.Pada riset ini, biodiesel akan diberikan aditif pyrogallol dan glycerol monostearate. Penambahan pyrogallol dilakukan dengan konsentrasi tetap pada seluruh sampel, sementara konsentrasi glycerol monostearate divariasikan. Karakteristik biodiesel yang dilihat untuk melihat stabilitas oksidasi adalah bilangan asam dan viskositas selama enam belas hari penyimpanan.Hasil penelitian menunjukkan penambahan glycerol monostearate dapat meningkatkan dispersi pyrogallol dalam biodiesel dan meningkatkan kinerja pyrogallol dalam menahan perubahan karakteristik biodiesel terkait oksidasi. Terdapat pengaruh perbedaan konsentrasi surfaktan glycerol monostearate terhadap penambahan kinerja antioksidan pyrogallol dimana penambahan glycerol monostearate 300 ppm dan pyrogallol sebesar 1000 ppm rasio 3:10 merupakan penambahan yang dapat mempertahankan karakteristik biodiesel paling baik.

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The utilization of biodiesel in Indonesia today isn rsquo t fully applied because of its vulnerability to oxidation. One of the way to counter this problem is by adding antioxidant. Pyrogallol is a widely used antioxidant for biodiesel but its difference in polarity flawed its solubility. The distribution of pyrogallol in biodiesel needs to be increased by adding surfactant. Surfactant is a type of compounds used to increase the dispersion of two compounds with different polarity. Glycerol monostearate is a type of surfactant commonly used to mix polar additives with palm oil.

In this research, biodiesel is given pyrogallol and glycerol monostearate as additives. Pyrogallol is added in same concentration for all samples, while glycerol monostearate concentration is varied. The characteristics of biodiesel used to determine oxidation stability is acid number and viscosity within sixteen days of storage.

The result shows that the addition of glycerol monostearate can increase the dispersion of pyrogallol in biodiesel and improve the antioxidant activity of pyrogallol. An effect of glycerol monostearate concentration to the improvement of antioxidant activity of pyrogallol is also detected, where the addition of 300 ppm glycerol monostearate and 1000 ppm pyrogallol ratio 3 10 is the best to improve oxidation stability of biodiesel."

"ABSTRACTPemerintah Indonesia menargetkan pada tahun 2020 konsentrasi biodiesel dalam campuran bahan bakar minyak jenis solar Biosolar harus mencapai angka 30. Namun, untuk saat ini konsentrasi biodiesel yang lebih dari 20 bersifat tidak stabil dan mudah teroksidasi. Untuk meningkatkan stabilitas oksidasi perlu dilakukan modifikasi komponen biodiesel. Salah satu caranya yaitu dengan reaksi hidrogenasi parsial. Hidrogenasi parsial memecah sebagian ikatan tak jenuh pada biodiesel yang merupakan komponen kunci penentuan sifat oksidatif. Hidrogenasi parsial dengan kondisi operasi tekanan 10 bar, suhu 150 OC, rasio katalis 5 berhasil menurunkan bilangan iodin yang semula 113,35 menjadi 101,54 dengan stabilitas oksidasi H-FAME sebesar 880 menit. Katalis yang digunakan untuk Hidrogenasi Parsial adalah NiMo/Zeolit.

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ABSTRACTIndonesian Government targets that by 2020 the concentration of biodiesel in diesel fuel mix Biosolar have to reach 30. However, the current issue is that more than 20 biodiesel concentration is unstable and easily oxidized. To improve oxidation stability it is necessary to modify the biodiesel component. One way is by partial hydrogenation reaction. Partial hydrogenation breaks up some unsaturated bonds in biodiesel which is a key component of the determination of oxidative properties. Partial Hydrogenation at 10 bar, 150 oC, and catalyst ratio 5 can decrease iodine number of unsaturated bond from 113,35 to 101,54 g I2 100g with oxidation stability of H FAME for 880 minutes. The catalyst that used in Partial Hydrogenation is NiMo Zeolith."

"Biodiesel merupakan bahan bakar yang berasal dari turunan minyak sayur dan lemak hewan yang dapat digunakan sebagai alternatif bahan bakar mesin diesel. Biodiesel memiliki kekurangan yaitu mudah teroksidasi yang disebabkan oleh adanya ikatan hidrokarbon sehingga dapat menurunkan kualitas biodiesel. Salah satu cara untuk mempertahankan stabilitas oksidasi biodiesel yaitu dengan penambahan antioksidan. Pyrogallol merupakan antioksidan yang paling efektif untuk mencegah oksidasi pada biodiesel. Akan tetapi, pyrogallol memiliki polaritas yang berbeda dengan biodiesel sehingga pyrogallol tidak dapat larut dan tidak terdispersi. Dibutuhkan modifikasi terhadap pyrogallol agar memiliki polaritas yang mendekati biodiesel. Penelitian sebelumnya menunjukkan bahwa reaksi antara pyrogallol dan methyl linoleate murni dengan senyawa radikal 2,2 diphenyl-1-picrylhydrazyl (DPPH) membentuk derivat pyrogallol terbukti dapat meningkatkan kelarutan pyrogallol pada biodiesel. Namun, methyl linoleate murni jika diaplikasikan pada skala industri tidak ekonomis. Pada penelitian ini, digunakan biodiesel jagung hasil transesterifikasi dari minyak jagung sebagai sumber methyl linoleate pengganti mehyl linoleate murni. Uji GCMS (Gas Chromatography-Mass Spectrometry) menunjukkan bahwa biodiesel jagung memiliki kandungan methyl linoleate sebesar 47,27 %. Sintesis dilakukan dengan mereaksikan 10 ml biodiesel, 5 ml DPPH, dan 5 ml pyrogallol. Keberadaan senyawa derivat pyrogallol ditunjukkan dengan terbentuknya spot baru pada TLC dan adanya pergeseran bilangan gelombang gugus C-O pada FTIR. Sintesis menghasilkan senyawa yang memiliki berat molekul 622,54 g/mol dengan yield 10,47% yang menunjukkan senyawa tersebut terdiri dari pyrogallol dan methyl linoleate. Berdasarkan pengukuran spektrofotometer UV-Vis, penambahan senyawa derivat pyrogallol ke dalam biodiesel kelapa sawit (B100) menghasilkan selisih absorbansi yang lebih kecil dibandingkan pyrogallol murni yang menunjukkan bahwa derivat pyrogallol lebih larut dalam biodiesel. Penambahan senyawa derivat pyrogallol ke dalam biodiesel kelapa sawit (B100) meningkatkan periode induksi (Induction Period) dan menghambat penurunan bilangan iodin.

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Biodiesel is a fuel derived from vegetable oil and animal fat derivatives that can be used as an alternative to diesel engine fuel. Biodiesel has the disadvantage of being easily oxidized due to hydrocarbon bonds which can reduce the quality of biodiesel. One way to maintain the stability of biodiesel oxidation is by adding antioxidants. Pyrogallol is the most effective antioxidant to prevent oxidation in biodiesel. However, pyrogallol has a different polarity from biodiesel so that pyrogallol is insoluble and undispersed. A modification to pyrogallol is needed to have a polarity close to biodiesel. Previous research has shown that the reaction between pyrogallol and pure methyl linoleate with the radical compound 2,2 diphenyl-1-picrylhydrazyl (DPPH) forming pyrogallol derivatives has been proven to increase the solubility of pyrogallol in biodiesel. However, pure methyl linoleate if applied on an industrial scale is not economical. In this study, corn biodiesel made by transesterification from corn oil is used as a source of methyl linoleate instead of pure mehyl linoleate. GCMS (Gas Chromatography-Mass Spectrometry) test shows that corn biodiesel has 47.27% methyl linoleate content. Synthesis was carried out by reacting 10 ml of biodiesel, 5 ml of DPPH, and 5 ml of pyrogallol. The existence of pyrogallol derivative compounds is indicated by the formation of new spots on TLC and the shifting of C-O groups in FTIR. Synthesis produces compounds which have a molecular weight of 622.54 g/mol with a yield of 10.47% which indicates the compound consists of pyrogallol and methyl linoleate. Based on UV-Vis spectrophotometer measurements, the addition of pyrogallol derivative compounds into palm oil biodiesel (B100) results in a smaller absorbance difference than pure pyrogallol which shows that pyrogallol derivatives are more soluble in biodiesel. The addition of pyrogallol derivative compounds into palm oil biodiesel (B100) increases the induction period and inhibits the decrease in iodine number."

"Biodiesel merupakan salah satu energi alternatif terbarukan yang berasal dari bahan bakar fosil biologis. Biodiesel memiliki sifat mudah teroksidasi sehingga biodiesel mengalami Penurunan kualitas. Beberapa antioksidan digunakan untuk meningkatkan stabilitas biodiesel. PY adalah aditif antioksidan yang paling efektif. Tapi PY \dan biodiesel memiliki polaritas yang berbeda sehingga tidak dapat terdistribusi dengan baik. Beberapa penelitian telah dilakukan dengan menggunakan kombinasi biner dari berbagai antioksidan. Upaya lain dilakukan dengan menambahkan surfaktan. Pada penelitian ini dilakukan penambahan surfaktan Dalam campuran antioksidan biner PY dan TBHQ, surfaktan yang ditambahkan adalah SMO dan GMS dengan variasi konsentrasi 200, 400 dan 600 ppm. Tes dispersi menunjukkan bahwa surfaktan dapat meningkatkan dispersi antioksidan biner dalambiodiesel. Peningkatan dispersi antioksidan dapat meningkatkan stabilitas oksidasi dibuktikan dengan peningkatan dispersi antioksidan 0,06% mampu meningkatkan periode induksi 2,44 jam. Penambahan surfaktan lebih dari 200 ppm terbukti menimbulkan endapan coklat tua. Komposisi optimal diperoleh pada penambahan surfaktan SMO dengan konsentrasi 200 ppm dengan periode induksi 39,74 jam dan komposisi tidak menimbulkan sedimen. Peningkatan stabilitas oksidasi biodiesel disebabkan oleh peningkatan dispersi disebabkan oleh peningkatan dispersi antioksidan karena interaksi sinergis antara PY, TBHQ dan SMO dibuktikan dengan adanya gugus C=O melalui uji FTIRBiodiesel is a renewable alternative energy derived from biological fossil fuels. Biodiesel has the property of being easily oxidized so that biodiesel has decreased in quality. Several antioxidants are used to increase the stability of biodiesel. PY is the most effective antioxidant additive. But PY \ and biodiesel have different polarities so they can't be distributed properly. Several studies have been conducted using binary combinations of various antioxidants. Another attempt was made by adding surfactants. In this study, surfactant was added. In a mixture of binary antioxidants PY and TBHQ, the surfactants added were SMO and GMS with varying concentrations of 200, 400 and 600 ppm. Dispersion tests showed that surfactants could increase the dispersion of binary antioxidants in biodiesel. Increasing antioxidant dispersion can increase oxidation stability as evidenced by an increase in antioxidant dispersion of 0.06% which can increase the induction period of 2.44 hours. The addition of surfactants of more than 200 ppm was proven to cause dark brown deposits. The optimal composition was obtained by adding SMO surfactant with a concentration of 200 ppm with an induction period of 39.74 hours and the composition did not cause sediment. The increase in the oxidation stability of biodiesel was caused by the increase in dispersion caused by the increase in antioxidant dispersion due to the synergistic interaction between PY, TBHQ and SMO as evidenced by the presence of C=O groups through the FTIR test."

"ABSTRAKAlam Indonesia kaya dengan kelapa sawit menjadikan kelapa sawit memiliki potensi besar untuk diajdikan bahan baku pembuatan biodiesel. Walaupun, biodiesel dari minyak kelapa sawit lebih stabil dari minyak lainnya tetapi pasti ada reaksi oksidasi dalam penyimpanan, sehingga tidak dapat memenuhi spesifikasi biodiesel yang disyaratkan pada SNI 7182-2015 yaitu minimal 48 jam. Pada penelitian ini, biodiesel yang disintesis dengan bahan baku minyak kelapa sawit melalui proses tahapan transesterifikasi dilakukan penambahan anti oksidan yaitu pyrogallol dengan rentang konsentrasi 500 ndash; 2000 ppm serta periode pengamatan 1 ndash; 3 minggu. Pyrogallol digunakan untuk penambahan antioksidan karena memiliki efektifitas yang tinggi untuk meningkatkan kestabilan oksidasi biodiesel. Kestabilan oksidasi biodiesel diamati pengujian densitas, angka asam, stabilitas oksidasi dan viskositas kinematic. Penambahan antioksidan pyrogallol 1500 ppm mampu menghambat terjadinya oksidasi biodiesel sampai lebih dari 48 jam yang merupakan kestabilan oksidasi maksimum di minggu ke 2.

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ABSTRAK

Indonesia have plentiful oil palm, which oil palm has great potential for biodiesel production as raw materials. Meanwhile, plm oil biodiesel is more stable than other oil although there must be oxidation reaction in storage, so it can not meet biodiesel specification that is not in SNI 7182 2015 that is at least 48 hours. In this study, biodiesel which is synthesized with palm oil raw materials through the process of transesterification stage is done by addition of anti oxidant that is pyrogallol with concentration range 500 2000 ppm and observation period 1 3 weeks. Pyrogallol is used for the addition of antioxidants because it has a high effectiveness to improve the oxidation stability of biodiesel. The stability of oxidation of biodiesel was observed by density test, acid number, oxidation stability and kinematic viscosity. The addition of 1500 ppm pyrogallol antioxidant can inhibit oxidation of biodiesel up to more than 48 hours which is stability in two week."

"ABSTRAKSebuah penelitian komparatif berbasis simulasi telah dilakukan untuk menyesuaikan dan memvalidasi model kinetika pembakaran dari surogat biodiesel dan solar, dan untuk menggabungkan kedua model tersebut untuk memprediksi waktu tunda ignisi IDT dari campuran biodiesel dan solar nyata. Penelitian ini meliputi pengembangan model kinetika pembakaran dari surogat biodiesel dan surogat solar, penggabungan kedua model tersebut, dan validasi dengan data eksperimen IDT dari setiap bahan bakar yang bersesuaian. Model kinetika pembakaran surogat biodiesel dan solar telah disesuaikan dan divalidasi agar cocok dengan data eksperimen IDT dari metil 9-dekenoat pada tekanan 20 atm dan tiga nilai rasio ekuivalensi dengan IDT sebesar 2.7 ms pada simulasi dan 2.69 ms pada data eksperimen , dan dari n-heksadekana pada 2 - 5 atm dan rasio ekuivalensi 1.0 dengan IDT sebesar 0.37 ms dari simulasi dan 0.38 ms pada data eksperimen . Model kinetika pembakaran gabungan telah dibuat dengan memakai model surogat biodiesel dan solar untuk memprediksi IDT dari campuran biodiesel dan solar nyata. Model ini sudah divalidasi agar cocok dengan data eksperimen IDT dari campuran biodiesel dan solar nyata pada empat komposisi campuran B20, B40, B60, B80 , tekanan 1.18 atm, dan menghasilkan model yang valid dengan IDT sebesar 0.699 ms dari simulasi dan 0.69 ms pada data eksperimen .

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ABSTRACTcomparative simulation based research has been set up to adjust and validate combustion kinetic models of biodiesel and solar surrogate and to combine the two models to predict ignition delay times IDT of real biodiesel and solar mixtures. This research consists of the development of combustion kinetics model for biodiesel surrogate and solar surrogate, the fusion of said models, and validation with the corresponding IDT experimental data for each fuel surrogates. Biodiesel and diesel combustion kinetic models have been adjusted and validated to fit the experimental IDT data of methyl 9 decenoate at 20 atm and three equivalence ratio values with IDT values of 2.7 ms from simulation and 2.69 ms from experimental data , and n hexadecane at pressure values of 2 5 atm and equivalence ratio of 1.0 with IDT values of 0.37 ms from simulation and 0.38 ms from experimental data . A combined combustion kinetic model has been made using biodiesel and solar surrogate models to predict the IDT of real biodiesel and solar mixtures. The model has been validated to fit the experimental IDT of real biodiesel and solar mixtures at four mixture compositions B20, B40, B60, B80 and 1.18 atm of pressure, resulting in a valid model with IDT values of 0.699 ms from simulation and 0.69 ms from experimental data ."

"The use of Waste Cooking Oil (WCO) as feedstock, and microwave heating technology are favored to reduce the cost of biodiesel. In order to identify the effect of using biodiesel from WCO Methyl Ester (WCOME) blends on diesel engine emissions and performance, WCOME blends were tested in a single-cylinder Direct Injection (DI) diesel engine at a constant speed of 2500 rpm and with five loads. For comparison, commercial diesel fuel, Petron Diesel Max (PDM), and biodiesel mixture from palm oil (POME) were also used. The performance and emission test results of the five test fuels: PDM, BP10, BP20, BW10, and BW20 were then compared with simulation results created by using GT-Power software. The experimental results indicated that using POME and WCOME blends led to increments in Brake Specific Fuel Consumption (BSFC) of up to 5.9% and reduction in Brake Thermal Efficiency (BTE) of up to 29.3% compare to PDM. These biodiesel blends also increased nitrogen oxide emissions and decreased carbon dioxide, carbon monoxide and hydrocarbon emissions for all engine loads at a constant speed of 2500 rpm. The experimental testing of the cylinder peak pressure demonstrates significant increase with the increase of engine load for the four test fuels. All the simulation graphs show similar trends."

"Pada penelitian ini, potensial pembentukan deposit dari bahan bakar biodiesel dengan formulasi berbeda dikaji dengan melakukan proses deposisi dan evaporasi bahan bakar secara berulang pada plat panas stainless steel (SS). Variasi aditif antioksidan dan bahan baku biodiesel dilakukan untuk mengetahui efek yang ditimbulkan terhadap pembentukan deposit. Antioksidan yang digunakan adalah PG, BHA dan BHT, sedangkan bahan baku biodiesel yang divariasikan adalah biodiesel sawit dan biodiesel jarak. Karakterisasi deposit pada plat dilakukan dengan menggunakan FTIR.Hasil FTIR deposit biodiesel sawit menunjukkan adanya kemiripan gugus fungsi bila dibandingkan dengan deposit yang terbentuk pada injektor dari data referensi. Biodiesel sawit yang memiliki ikatan tidak jenuh dan angka asam lebih kecil menghasilkan deposit yang jauh lebih sedikit bila dibandingkan dengan biodiesel jarak dengan ikatan tak jenuh dan angka asam yang tinggi. Penambahan aditif antioksidan pada biodiesel dengan kadar 1000 ppm tidak menyebabkan perubahan beberapa sifat fisik biodiesel secara berarti, meningkatkan stabilitas oksidasi & cenderung menurunkan jumlah deposit yang terbentuk pada plat SS. Biodiesel sawit dan aditif antioksidan BHT dipilih untuk dilakukan pengujian pada engine yang dilakukan selama 70 jam (10 jam perhari) dengan beban konstan  70% load. Efek penambahan aditif BHT pada engine mampu menurunkan emisi smoke sebesar 24%, sedangkan efek terhadap pembentukan deposit bervariasi tergantung komponen tempat terbentuknya deposit. Penurunan deposit terjadi pada piston, silinder head dan exhaust valve berturut turut : 32%, 8% dan 23% , kenaikan deposit terjadi pada intake valve sebesar 11%, dan pada injektor tip berdasarkan data fotografi.

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In this study, the potential of deposits formation of biodiesel fuels with different formulation studied by conducting the repetitive process of fuel deposition and evaporation on stainless steel (SS) hot plate. Variation of antioxidant additives and biodiesel feedstock was conducted to determine the effects on the deposits formation. Antioxidants used were PG, BHA and BHT, while the biodiesel feedstocks were Palm biodiesel and Jathropha biodiesel. Characterization of the deposit on the plate has been done by using FTIR.The result of FTIR showed that deposits of Palm biodiesel on hot plate have similar functional groups compared to deposits on the injector based on the literature data. Palm biodiesel with low unsaturated bond & acid number produced fewer deposits than Jathropa biodiesel with high unsaturated bond & acid number. The addition of 1000 ppm antioxidant were increasing the oxidation stability and reducing the amount of deposits that form on the plate, but not altering the physical properties of biodiesel significantly. Palm biodiesel and antioxidant BHT were selected for testing on the engine which performed for 70 hours (10 hours per day) with a constant load  70% load. BHT additive could reduce smoke emissions by 24%, while the effect on the formation of deposits was varied depend on the component where deposit formed. The decrease deposits formation occurred on the piston, cylinder head and exhaust valve respectively: 32%, 8% and 23%, whereas the increase ones occurred on the intake valve by 11%. There was also an increase deposit occured on the injector tip based on photography data."

"Akibat meningkatnya pemakaian dan harga minyak bumi pada akhir-akhir ini, persediaan minyak semakin menipis dan rnasaiah dampak lingkungan yang diakibatkannya sehingga diversifikasi bahan bakar sangat dibutuhkan. Biodiesel salah satu alternatif bahan bakar memberi harapan karena merupakan energi terbarukan dan ramah lingkungan. Pengolahan biodiesel minyak kelapa dan minyak jagung dilakukan secara transesterifikasi menggunakan pereaksi spiritus dengan prosesor jenis susun.Hasil proses transesterifikasi ini diperoleh karakteristik kedua biodiesel tersebut menyerupai minyak solar setelah uji propertis laboratorium. Saiah satu propertis yang paling menonjol dari biodiesel ini, memiliki bilangan Setana lebih tinggi dari minyak solar. Dengan metoda pencampuran dengan minyak solar sebesar 10 % sampai 30 %, pengaruh biodiesel ini berkontribusi terhadap peningkatan bilangan Setana campuran antara 2,3 % sampai 13 %, tingginya bilangan Setana ini membantu meningkatkan kualitas penyalaan, performa mesin dan menurunkan emisi gas buang (opasitas). Formulasi campuran biodiesel minyak kelapa dan minyak jagung yang digunakan adalah 1310, B20 dan 1330. Pengujian performa mesin dilakukan pada Engine Research and Test Bed Mesin Nissan tipe SD-22 tanpa modifikasi mesin (standard). Pengujian dilakukan pada variasi putaran (rpm) dan variasi bukaan throttle (%).Dari basil pengujian diperoleh bahwa pengaruh biodiesel kelapa dan jagung terhadap performa mesin meliputi pemakaian spesifik bahan bakar, brake horse power, efisiensi thermal secara umum masih dibawah performa minyak solar. Perbedaan signifikan terjadi pada level opasitas, dengan penambahan konsentrasi biodiesel penurunan opasitas berkurang sampai 40,7 %. Secara umum dari variasi campuran diantara kedua jenis biodiesel tersebut, B20 Kelapa memiliki basil yang paling baik.

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The recent increase in petroleum consumption and world petroleum price, gradual depletion of world petroleum reserves and the impact of environmental problems so that fuel diversification hardly is required. Biodiesel is a promising alternative because it is renewable energy and environ-friendly. In this research, processing of biodiesels of coconut oil and corn oil were processed by using processor series type with transesterification process.

From result obtained properties almost same as diesel oil properties. One of the both biodiesel properties have higher cetane number as compared from cetane number of pure diesel oil. By adding biodiesel concentration 10 % to 30 %, the new cetane number of blending increased 2,3 % to 13 %. The improvement of cetane number effected combustion quality, engine performance and exhaust gas emission (opacity level). The biodiesel blending formulations in this research are 1310, B20 and B30. Engine performance test was conducted on Engine Research and Test Bed with Nissan tipe SD-22 at variated rotational engine speed (rpm) and throttle valve open (%) without any engine modification.

The result showed that the effect of biodiesel blends gave fuel consumption, specific fuel consumption, brake horse power and thermal efficiency, generally less than from diesel oil engine performance. The biggest difference happened at opacity level where by adding biodiesel concentration the opacity level decreased around 40,7 % from diesel oil. From all blending variations, the best result is B20 Coconut Oil."