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"Mengisolir logam dari bahan korosi merupakan cara yang paling efektif untuk mencegah korosi pada industri minyak dan gas bumi. Penggunaan inhibitor korosi organik menjadi alternatif baru untuk mencapai tujuan tersebut. Penelitian ini dilakukan untuk mempelajari perilaku inhibisi ekstrak ubi ungu menggunakan metode perendaman. Selain itu pada penelitian ini juga akan dibahas studi mengenai inhibisi pada dua lingkungan yang berbeda dengan metode polarisasi. Untuk karakterisasi sampel digunakan FTIR, OES, OM, hingga software LENNTECH calculator, serta program NOVA 1.8 dengan mesin AUTOLAB PGSTAT. Pada pengujian perendaman, laju korosi menurun seiring dengan pertambahan waktu perendaman. Pada proses polarisasi laju korosi turun dan mencapai maksimum dengan penambahan 4ml ekstrak ubi ungu pada polarisasi air formasi dan 12 ml pada polarisasi air formasi cepu. Efisiensi inhibisi ekstrak ubi ungu mencapai 53,5% merupakan nilai inhibisi optimal yang didapatkan pada air formasi, dan 83,5% pada ari formasi cepu . Berdasarkan Kurva Polarisasi, Ecorr dan Icorr dapat disimpulkan bahwa ekstrak ubi ungu memiliki kecenderungan mekanisme inhibitor anodik dengan adannya lapisan pasif. Mekanisme inhibitor anodik dengan kecenderungan lapisan pasif menjadi bukti penting mekanisme inhibisi ekstrak ubi ungu

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Isolate the metal from corrosion of materials is the most effective way to prevent corrosion in oil and gas industry. The use of green corrosion inhibitor become a new alternative to achieve that goal. This study was conducted to study the inhibition behavior of sweet potato extract, using the immersion method and inihibition study at two different condition using polarization method. For characterizing of samples are used FTIR, OES, OM, LENNTECH calculator software, and NOVA 1.8 software with AUTOLAB PGSTAT machine. In study using immersion method, corrosion rate decreased with added time of immersion. Corrosion rate decreased and reached a maximum with the addition of 4 ml sweet potato extract (connate water) and 12 ml of sweet potato extract (cepu’s connate water). Inhibition efficiency of sweet potato extract reach 53,40% (connate water) and inhibition efficiency of sweet potato extract reach 83,5% (cepu’s connate water). Based on the polarization curve, Ecorr, current density, it can be concluded that the sweet potato extract has a mechanism of anodic inhibitor, to block reaction at metal surface. The anodic mechanism which existence of passive film becomes important evidence of inhibition mechanism of sweet potato extract."

"Korosi adalah degradasi material akibat interaksi dengan lingkungan, dimana menyebabkan material mengalami kegagalan dan kerugian. Salah satu cara yang paling efektif dalam mencegah kerugian akibat korosi pada industri minyak dan gas bumi adalah mengisolir logam dari lingkungannya. Penggunaan inhibitor korosi berbahan alami menjadi salah satu alternatif baru untuk mencapai tujuan tersebut. Telah dilakukan penelitian dalam mempelajari perilaku inhibisi air rendaman kulit sawo dalam lingkungan air formasi terhadap baja API 5L menggunakan metode kehilangan berat dengan variabel waktu rendaman (3, 6, 9, dan 12 hari) dan konsentrasi inhibitor 30 ml. Penggunaan air rendaman kulit sawo sebagai inhibitor organik didasari oleh adanya kandungan senyawa antioksidan di dalamnya berupa gugus phenolik, yaitu senyawa tannin. Hasil penelitian menunjukkan hasil yang baik, dimana air rendaman kulit sawo mampu menurunkan laju korosi dengan efisiensi sebesar 80,85% pada hari ke-3 perendaman dan turun sampai 58,30% pada hari ke-12 perendaman. Terbentuknya lapisan tipis tidak kasat mata ferric tannate pada permukaan sampel menunjukkan mekanisme inhibisi inhibitor kulit sawo, dengan mekanisme adsorpsi campuran sebagai cara senyawa tannin melakukan inhibisi.

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Corrosion is the degradation of the material due to interaction with the environment, which lead to material failure and loss. One of the most effective ways to prevent losses due to corrosion in the oil and gas industry is to isolate the metal from the environment. The use of corrosion inhibitor made from natural become one of the new alternatives to achieve these objectives.

Has conducted research in the study of behavioral inhibition of sapodilla skin soaking water in connate water environment of the API 5L steel using weight loss method with immersion time variable (3, 6, 9, and 12 days) and the concentration of inhibitor is 30 ml. The use of sapodilla skin water soaking as organic inhibitors based on the content of antioxidant compounds in the form of phenolic group, the tannin compounds.

A good results showed, with sapodilla skin soaking water can reduce the corrosion rate with an efficiency of 80.85% on the 3rd day of immersion and dropped to 58.30% on the 12th day of immersion. The formation of a invisible thin layer of ferric tannate on the surface of the samples showed inhibition mechanism of sapodilla skin inhibitor, with a mixture adsorption mechanism as the way of doing the inhibition from tannin compounds."

"Mengisolir logam dari bahan korosi merupakan adalah cara yang paling efektif untuk mencegah korosi pada industri minyak dan gas bumi. Penggunaan inhibitor korosi alami menjadi alternatif baru untuk mencapai tujuan tersebut. Penelitian ini dilakukan untuk mempelajari perilaku inhibisi ekstrak ubi ungu dan dibandingkan dengan inhibitor kimia, menggunakan metode polarisasi. Penelitian ini dilakukan untuk mempelajari perilaku inhibisi ekstrak ubi ungu dengan dibandingkan dengan inhibitor kimia, menggunakan metode polarisasi. Untuk karakterisasi sampel digunakan FTIR, OES, OM, hingga software LENNTECH calculator, serta program NOVA 1.8 dengan mesin AUTOLAB PGSTAT. Laju korosi turun dan mencapai maksimum dengan penambahan 4 ml ekstrak ubi ungu dan 2 ml pada inhibitor kimia. Efisiensi inhibisi ekstrak ubi ungu mencapai 53,54% merupakan nilai inhibisi optimal yang didapatkan. Berdasarkan Kurva Polarisasi, Ecorr dan Icorr dapat disimpulkan bahwa ekstrak ubi ungu dan inhibitor kimia memiliki kecenderungan mekanisme inhibitor anodik dengan adannya lapisan pasif. Mekanisme inhibitor anodik dengan kecendrungan lapisan pasif menjadi bukti pentinng mekanisme inhibisi ekstrak ubi ungu.

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Isolate the metal from corrosion of materials is the most effective way to prevent corrosion in oil and gas industry. The use of green corrosion inhibitor become a new alternative to achieve that goal. This study was conducted to study the inhibition behavior of sweet potato extract and compared with chemical inhibitor, using the polarization method.

This study was conducted to study the inhibition behavior of sweet potato extract and compared with chemical inhibitor, using the polarization method. For characterizing of samples are used FTIR, OES, OM, LENNTECH calculator software, and NOVA 1.8 software with AUTOLAB PGSTAT machine.

Corrosion rate decreased and reached a maximum with the addition of 4 ml sweet potato extract and 2 ml of chemical inhibitor. Inhibition efficiency of sweet potato extract reach 53,54%. Based on the polarization curve, Ecorr, current density, it can be concluded that the sweet potato extract has a mechanism of anodic inhibitor, to block reaction at metal surface. The anodic mechanism which existence of passive film becomes important evidence of inhibition mechanism of sweet potato extract."

"Mengisolir logam dari bahan korosi merupakan adalah cara yang paling efektif untuk mencegah korosi pada industri minyak dan gas bumi. Penggunaan inhibitor korosi alami menjadi alternatif baru untuk mencapai tujuan tersebut. Bahan alam dipilih sebagai alternatif karena bersifat aman, mudah didapatkan, bersifat biodegradable, biaya murah, dan ramah lingkungan. Penelitian ini dilakukan untuk mempelajari perilaku inhibisi ekstrak kulit sawo & dibandingkan dengan inhibitor kimia, menggunakan metode polarisasi. Untuk karakterisasi sampel digunakan FTIR, OES, OM, hingga software LENNTECH calculator, serta program NOVA 1.8 dengan mesin AUTOLAB PGSTAT. Laju korosi turun dan mencapai maksimum dengan penambahan 8ml ekstrak kulit sawo dan 2ml inhibitor kimia. Efisiensi inhibisi ekstrak kulit sawo mencapai 43,02% akibat kondisi pH yang tidak optimal (antara 4,6 hingga 5,9). Berdasarkan Kurva Polarisasi, Ecorr, Rapat Arus, dan Resistansi Polarisasi, dapat disimpulkan bahwa ekstrak kulit sawo memiliki mekanisme adsorpsi (inhibitor anodik) dan inhibitor kimia dengan mekanisme adsorpsi dan sekedar memblokir reaksi pada permukaan logam. Terbentuknya deposit ferric tannate pada permukaan logam menjadi bukti penting terhadap mekanisme inhibisi ekstrak kulit sawo, yang mengandung senyawa tannin.

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Isolate the metal from corrosion of materials is the most effective way to prevent corrosion in oil and gas industry. The use of green corrosion inhibitor become a new alternative to achieve that goal. Green inhibitor chosen as an alternative because it is safe, easily available, biodegradable, low cost, and environmentally friendly.

This study was conducted to study the inhibition behavior of sapodilla skin extract and compared with chemical inhibitor, using the polarization method. For characterizing of samples are used FTIR, OES, OM, LENNTECH calculator software, and NOVA 1.8 software with AUTOLAB PGSTAT machine.

Corrosion rate decreased and reached a maximum with the addition of 8 ml sapodilla skin extract and 2 ml of chemical inhibitor. Inhibition efficiency of sapodilla skin extract reach 43,02%, due to pH condition are not optimal (between 4,6 to5,9 ). Based on the polarization curve, Ecorr, current density, and polarization resistance, it can be concluded that the sapodilla skin extract has a mechanism of adsorption (anodic inhibitor) and chemical inhibitor with the mechanism of adsorption, to block reaction at metal surface. Formation of ferric tannate deposition on metal surface become important proof for the mechanism of inhibition sapodilla skin extract, which containing tannin compound."

"Korosi merupakan penyebab utama kegagalan dalam industri minyak dan gas bumi. Mengisolir logam dari bahan korosi merupakan adalah cara yang paling efektif untuk mencegah korosi pada industri ini. Penggunaan inhibitor korosi alami menjadi alternatif baru untuk mencapai tujuan tersebut. Bahan alam dipilih sebagai alternatif karena bersifat aman, mudah didapatkan, bersifat biodegradable, biaya murah, dan ramah lingkungan.Penelitian ini dilakukan untuk mempelajari perilaku inhibisi ekstrak kulit manggis pada pipa baja API-5L di lingkungan air terproduksi dan dibandingkan dengan inhibitor kimia dengan menggunakan metode kehilangan berat. Parameter elektrokimia dievaluasi dengan menggunakan metode EIS dan metode FTIR dilakukan untuk mengidentifikasi gugus aktif yang bekerja. Ekstrak kulit manggis dipilih sebagai inhibitor korosi karena mengandung senyawa antioksidan yang dapat menghambat laju korosi. Hasil penelitian menunjukkan ekstrak kulit manggis dan inhibitor kimia merupakan inhibitor korosi yang sangat efektif untuk pipa baja API-5L di lingkungan air terproduksi karena dapat menurunkan laju korosi secara signifikan. Efisiensi inhibisi ekstrak kulit manggis sebesar 58 - 92% dengan penambahan 2 - 10 ml ekstrak kulit manggis. Ekstrak kulit manggis bekerja dengan membentuk suatu lapisan tipis (terlihat maupun tidak terlihat secara kasat mata) atau senyawa kompleks, yang mengendap (adsorpsi) pada permukaan logam sebagai lapisan pelindung yang dapat menghambat reaksi logam tersebut dengan lingkungannya. Mekanisme ini juga didukung dengan meningkatnya nilai tahanan polarisasi dari permukaan baja setelah ditambahakan inhibitor.

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Corrosion is the major cause failure in oil and gas industry. Isolate the metal from corrosion of materials is the most effective way to prevent corrosion for this industry. The use of green corrosion inhibitor become a new alternative to achieve that goal. Green inhibitor chosen as an alternative because it is safe, easily available, biodegradable, low cost, and environmentally friendly.

This study was conducted to study the inhibition behavior of pericarp of mangosteen extract for API-5L pipe steel in produced water environment and compared with chemical inhibitor using the weight loss method Electrochemical parameters are evaluated using EIS method and FTIR method to identify functional group that works. Pericarp of mangosteen extract is selected as corrosion inhibitor because they contain antioxidant compounds that can inhibit the corrosion rate.

Result showed pericarp of mangosteen extract and chemical inhibitor is highly effective corrosion inhibitor for API-5L pipe steel in produced water environment because it can inhibit the corrosion rate significantly. Inhibition efficiency for pericarp of mangosteen is 58 - 92% with addition of pericarp of mangosteen extract of 2 -10 ml. Pericarp of mangosteen works by forming a thin layer (visible or not visible by naked eye) or complex compounds, which settles (adsorption) to metal surfaces as a protective layer that can inhibit the reaction of the metal with its environment. This mechanism is also supported by the increased value of the polarization resistance of the steel surface after addition of inhibitor."

"Korosi merupakan kegagalan yang sering terjadi pada industri minyak dan gas bumi Menghambat terjadinya korosi dengan mengisolir logam dari lingkungan terkorosi pada industri minyak dan gas bumi merupakan salah satu cara efektif untuk menghindari terjadi kegagalan korosi. Penggunaan inhibitor alami menjadi pihan utama belakang ini karena aman murah dan yang terpenting bahan tersebut biodegradable dan tidak berbahaya bagi lingkungan. Penelitian ini dilakukan untuk melihat efek dari penambahan teh rosella merah terhadap inhibitor ubi ungu yang memang dapat digunakan menjadi inhibitor pada baja API 5L pada lingkungan NaCl 3 5. Pengujian ini dilakukan dengan menggunakan metode kehilangan berat dan polarisasi untuk melihat laju korosi yang terjadi pada logam lalu dilengkapi dengan data tambahan yaitu pengujian Electrochemical Impedance Spectroscopy untuk melihat tahan permukaan yang berbubah pada penelitian tersebut. Pengujian Fourier Transform Infra Red juga dilakukan untuk melihat kandungan yang menginhibisi dari ubi ungu ataupun campuran ubi ungu dan teh rosella merah Pemilihan teh rosella merah dan ubi ungu berdasarkan kandungan antocyanin dan asam askorbat yang dimiliki kedua bahan tersebut Kandungan tersebut bersifat anti oksidan yang berarti dapat menghambat terjadi proses oksidasi yang berarti juga dapat mencegah korosi. Kandungan anti oksidan tersebut bekerja dengan cara adsoprsi pada permukaan logam membentuk lapisan tipis untuk mencegah kontak antara permukaan logam dengan lingkungan korosif. Salah satu faktor pembentukan lapisan tipis pada permukaan adalah konsentrasi kandungan tersebut sehingga pengaruh konsentrasi dijadikan acuan pada penelitian ini. Penelitian ini akan dibandingkan dengan inhibitor ubi ungu yang hanya dicampur dengan kandungan asam askorbat saja.

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Corrosion is major cause failure in oil ad gas industry Isolate the metal from corrosion of materials is the most effective way to prevent corrosion for this industry. Nowadays the use of green corrosion inhibitor become a new alternative to achieve that goal it happen because the green inhibitor is safe cheap biodegradable and especially environmental friendly.

This study was conducted to study the effect of addition rosella red tea in purple sweet potato inhibitor which is can be use as inhibitor at API 5L in NaCl 3 5 solution. This study use weight loss and polarization method to see that effect and Electrochemical Impedance Spectroscopy test to prove alteration surface resistance when we add the inhibitor.

Fourier Transform Infra Red test also perform in this study to see which one the chemical substance in purple sweet potato and mixture rosella red tea and purple sweet potato can inhibit corrosion. Purple sweet potato and rosella red tea are selected as corrosion inhibitor in this study because they contain antocyanin and ascorbid acid. They are antioxidant compound which is can inhibit oxidation process it means they can prevent corrosion process. That substance inhibit metal by forming layer and isolate metal surface On the important factor to forming thin layer is concentration of the substance so the concentration substance become variable in this study. In the end this study will compared with the addition ascorbid acid in purple sweet potato"

"[ABSTRAKKorosi pada tubing baja karbon merupakan masalah serius bagi eksplorasi dan produksi minyak dan gas. Perilaku korosi baja paduan rendah 3%Cr (3Cr) dan baja karbon J55 dalam lingkungan air formasi diinvesitigasi dengan menggunakan pengujian tafel polarisasi potensiodinamik, electrochemical impedance spectroscopy (EIS) dan pengamatan metalografi. Komposisi dan morfologi dari produk korosi kedua baja dianalisa dengan energy dispersive spectroscopy (EDS) dan scanning electron microscopy (SEM). Hasil pengujian memperlihatkan adanya korosi lokal pada baja J55 dengan struktur mikro pro-eutektoit ferit dan perlit, dan tidak terlihat pada baja 3Cr dengan struktur mikro martensit temper dikarenakan terbentuknya lapisan produk korosi kaya-Cr yang padat, kontinyu dan melekat dengan baik ke permukaan baja. Lapisan produk korosi yang bercelah dan tidak kontinyu pada baja J55 menyediakan jalan bagi ion-ion agresif untuk masuk dan menimbulkan korosi lokal pada permukaan baja.ABSTRACTCorrosion of carbon steel tubings is a serious problem for oil and gas wet exploration and production. Corrosion behaviour of low bearing 3%Cr (3Cr) alloy steel and J55 carbon steel in produced water were investigated by polarisation potentiodynamic tafel, electrochemical impedance spectroscopy (EIS) and metallography observation. The composition and morphology of corrosion products were analyzed by energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The results show that there was localized corrosion was observed in J55 carbon steel with pro-eutectoid ferrite and pearlite microstructure, which did not exist in 3Cr steel with tempered martensite microstructure due to formation of a dense, continuous and adherent Cr-rich scale on surface steel. Many pits in the less adherent corrosion scale of J55 carbon steel could build up ion-diffusion channels which would degrade the protective capabilities of the product films and aggravate localized corrosion.;Corrosion of carbon steel tubings is a serious problem for oil and gas wet exploration and production. Corrosion behaviour of low bearing 3%Cr (3Cr) alloy steel and J55 carbon steel in produced water were investigated by polarisation potentiodynamic tafel, electrochemical impedance spectroscopy (EIS) and metallography observation. The composition and morphology of corrosion products were analyzed by energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The results show that there was localized corrosion was observed in J55 carbon steel with pro-eutectoid ferrite and pearlite microstructure, which did not exist in 3Cr steel with tempered martensite microstructure due to formation of a dense, continuous and adherent Cr-rich scale on surface steel. Many pits in the less adherent corrosion scale of J55 carbon steel could build up ion-diffusion channels which would degrade the protective capabilities of the product films and aggravate localized corrosion.;Corrosion of carbon steel tubings is a serious problem for oil and gas wet exploration and production. Corrosion behaviour of low bearing 3%Cr (3Cr) alloy steel and J55 carbon steel in produced water were investigated by polarisation potentiodynamic tafel, electrochemical impedance spectroscopy (EIS) and metallography observation. The composition and morphology of corrosion products were analyzed by energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The results show that there was localized corrosion was observed in J55 carbon steel with pro-eutectoid ferrite and pearlite microstructure, which did not exist in 3Cr steel with tempered martensite microstructure due to formation of a dense, continuous and adherent Cr-rich scale on surface steel. Many pits in the less adherent corrosion scale of J55 carbon steel could build up ion-diffusion channels which would degrade the protective capabilities of the product films and aggravate localized corrosion., Corrosion of carbon steel tubings is a serious problem for oil and gas wet exploration and production. Corrosion behaviour of low bearing 3%Cr (3Cr) alloy steel and J55 carbon steel in produced water were investigated by polarisation potentiodynamic tafel, electrochemical impedance spectroscopy (EIS) and metallography observation. The composition and morphology of corrosion products were analyzed by energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The results show that there was localized corrosion was observed in J55 carbon steel with pro-eutectoid ferrite and pearlite microstructure, which did not exist in 3Cr steel with tempered martensite microstructure due to formation of a dense, continuous and adherent Cr-rich scale on surface steel. Many pits in the less adherent corrosion scale of J55 carbon steel could build up ion-diffusion channels which would degrade the protective capabilities of the product films and aggravate localized corrosion.]"

"[ABSTRAKPenelitian pemanfaatan ekstrak tumbuh-tumbuhan sebagai inhibitor korosibelakangan ini semakin meningkat seiring dengan meningkatnya permintaanpenggunaan bahan-bahan kimia yang ramah lingkungan. Pemanfaatan ekstraktumbuh-tumbuhan sebagai inhibitor korosi menjadi penting mengingatkarakteristiknya ramah lingkungan (green inhibitor), mudah ketersediaannnya,sumberdaya yang melimpah dan dapat diperbaharui, prosedur produksi yangsederhana, dan biaya produksi yang cukup kompetitif. Dalam penelitian inidilakukan pengujian eksperimental efek sinergis jenis inhhibitor baru yaituekstrak ubi ungu (Ipomoea batatas L.) yang memiliki kandungan utamaantosianin dengan inhibitor komersial berbasis amine (aniline) dan denganinhibitor asam askorbat.Penelitian bertujuan untuk menganalisis laju kororsi dan efisiensi inhibisikorosi logam baja (API 5L) di dalam lingkungan air terproduksi menggunakaninhibitor campuran ekstrak ubi ungu dan inhibitor komersial berbasis amine(aniline). Selain itu dilakukan pula analisis laju korosi, efisiensi inhibisi,mekanisme proteksi dan model lapisan inhibisi korosi logam baja (API 5L) didalam lingkungan 3,5% NaCl menggunakan inhibitor campuran ekstrak ubi ungudan asam askorbat.Metode pengukuran laju korosi dan efisiensi inhibisi dilakukanmenggunakan elektrokimia kurva polarisasi. Mekanisme korosi diteliti denganmenggunakan metode Electrochemical Impedance Spectroscopy (EIS). Untukmenganalisis model lapisan inhibisi dilakukan dengan menggunakan metodeFourier Transform Infra Red (FTIR) spectroscopy.Hasil penelitian menunjukan bahwa pencampuran ekstrak ubi ungumemiliki kemampuan sinergis dengan inhibitor komersial berbasis amine (aniline)pada fraksi volume ekstrak ubi ungu sebesar 25% dengan menghasilkan efisiensiinhibisi sebesar 82,14%. Sebagai pembanding, pada sistem yang samapenggunaan esktrak ubi ungu saja menghasilkan efisiensi inhibisi 68,30%,sedangkan penggunaan inhibitor komersial berbasis amine (aniline) sajamenghasilkan efisiensi inhibisi 74,88%.Penambahan volume ekstrak ubi ungu dari 1 mL hingga 4 mL kedalaminhibitor asam askorbat 10-4 M meningkatkan efisiensi inhibisi korosi logam baja(API 5L) dalam larutan 3,5% NaCl dari efisiensi inhibisi sebesar 23,37% menjadi57,52%. Campuran inhibitor korosi tersebut berpengaruh terhadap kurvapolarisasi anodik maupun katodik sehingga dapat berperan sebagai mixedinhibitor. Pengujian EIS menunjukan proses korosi dikontrol oleh mekanismepasivasi yang ditunjukan oleh adanya peningkatan tahanan permukaan korosi.Pada lapisan permukaan terjadi proses adsorpsi dan pembentukan kelatorgano (flavonoid) logam dimana ekstrak ubi ungu dengan kandungan utamaantosianin berperan sebagai pembentuk metal-chelated. Pembentukan kelatekstrak ubi ungu-Fe-asam askorbat terjadi pada gugus hidroksil dan karbonil.Lokasi terjadinya ligan kelat ekstrak ubi ungu dengan kandungan utma antosianinterjadi pada ikatan 3?, 4? Dihydroxy cincin B atau 3-Hydroxy 4-Carbonyl cincin C;

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ABSTRACTResearch of utilization of plant extracts as a corrosion inhibitor recentlyincreased along with the increasing demand for the use of chemicals that areenvironmentally friendly. Utilization of plant extracts as a corrosion inhibitorbecomes important given the characteristics of environmentally friendly (greeninhibitor), easy availability, resources are abundant and renewable, the productionprocedure is simple, and the production costs are quite competitive. In thisresearch, experimental testing of the synergistic effects of new types inhibitor ieextract purple potato (Ipomoea batatas L.) which has the main content ofanthocyanin with commercial inhibitor-based amine (aniline) and with ascorbicacid inhibitors.The study aims to analyze the rate of corrosion and metal corrosioninhibition efficiency of steel (API 5L) in the produced water environment using amixed inhibitor purple sweet potato extract and commercial-based inhibitors ofamine (aniline). In addition, the corrosion rate analysis was also performed,inhibition efficiency, protection mechanisms and models of metal corrosioninhibition layer steel (API 5L) in the neighborhood of 3.5% NaCl using a mixedinhibitor purple sweet potato extract and ascorbic acid.Method of measuring the rate of corrosion and inhibition efficiency wasperformed using electrochemical polarization curves. Corrosion mechanismsinvestigated by Electrochemical Impedance Spectroscopy (EIS). To analyze themodel layer of inhibition were calculated using Fourier Transform Infra Red(FTIR) spectroscopy.The results showed that mixing purple sweetpotato extract has the abilityto synergistically with commercial inhibitor-based amine (aniline) in purplesweetpotato extract volume fraction of 25% with a yield of 82.14% inhibitionefficiency. For comparison, the same system using purple sweet potato extractonly produce inhibition efficiency of 68.30%, while the use of commercial-basedinhibitors of amine (aniline) alone resulted in inhibition efficiency of 74.88%.The addition of purple sweet potato extract volume of 1 mL to 4 mL intoascorbic acid inhibitors 10-4 M improving steel metal corrosion inhibitionefficiency (API 5L) in a solution of 3.5% NaCl of inhibition efficiency of 23.37%to 57.52%. The corrosion inhibitor mixture affect the anodic and cathodicpolarization curves so that it can act as a mixed inhibitor. Testing EIS shows thecorrosion process is controlled by the passivation mechanism indicated by anincrease in the surface resistance of corrosion.On the surface layer of a process of adsorption and formation of organochelates (flavonoids) in which the metal purple sweet potato extract with the maincontent of anthocyanins act as forming metal-chelated. Location of the chelatingligand purple sweet potato extract with the main content of anthocyanins occur inbond 3 ', 4' dihydroxy ring B or 3-Hydroxy 4-Carbonyl ring C.;Research of utilization of plant extracts as a corrosion inhibitor recentlyincreased along with the increasing demand for the use of chemicals that areenvironmentally friendly. Utilization of plant extracts as a corrosion inhibitorbecomes important given the characteristics of environmentally friendly (greeninhibitor), easy availability, resources are abundant and renewable, the productionprocedure is simple, and the production costs are quite competitive. In thisresearch, experimental testing of the synergistic effects of new types inhibitor ieextract purple potato (Ipomoea batatas L.) which has the main content ofanthocyanin with commercial inhibitor-based amine (aniline) and with ascorbicacid inhibitors.The study aims to analyze the rate of corrosion and metal corrosioninhibition efficiency of steel (API 5L) in the produced water environment using amixed inhibitor purple sweet potato extract and commercial-based inhibitors ofamine (aniline). In addition, the corrosion rate analysis was also performed,inhibition efficiency, protection mechanisms and models of metal corrosioninhibition layer steel (API 5L) in the neighborhood of 3.5% NaCl using a mixedinhibitor purple sweet potato extract and ascorbic acid.Method of measuring the rate of corrosion and inhibition efficiency wasperformed using electrochemical polarization curves. Corrosion mechanismsinvestigated by Electrochemical Impedance Spectroscopy (EIS). To analyze themodel layer of inhibition were calculated using Fourier Transform Infra Red(FTIR) spectroscopy.The results showed that mixing purple sweetpotato extract has the abilityto synergistically with commercial inhibitor-based amine (aniline) in purplesweetpotato extract volume fraction of 25% with a yield of 82.14% inhibitionefficiency. For comparison, the same system using purple sweet potato extractonly produce inhibition efficiency of 68.30%, while the use of commercial-basedinhibitors of amine (aniline) alone resulted in inhibition efficiency of 74.88%.The addition of purple sweet potato extract volume of 1 mL to 4 mL intoascorbic acid inhibitors 10-4 M improving steel metal corrosion inhibitionefficiency (API 5L) in a solution of 3.5% NaCl of inhibition efficiency of 23.37%to 57.52%. The corrosion inhibitor mixture affect the anodic and cathodicpolarization curves so that it can act as a mixed inhibitor. Testing EIS shows thecorrosion process is controlled by the passivation mechanism indicated by anincrease in the surface resistance of corrosion.On the surface layer of a process of adsorption and formation of organochelates (flavonoids) in which the metal purple sweet potato extract with the maincontent of anthocyanins act as forming metal-chelated. Location of the chelatingligand purple sweet potato extract with the main content of anthocyanins occur inbond 3 ', 4' dihydroxy ring B or 3-Hydroxy 4-Carbonyl ring C., Research of utilization of plant extracts as a corrosion inhibitor recentlyincreased along with the increasing demand for the use of chemicals that areenvironmentally friendly. Utilization of plant extracts as a corrosion inhibitorbecomes important given the characteristics of environmentally friendly (greeninhibitor), easy availability, resources are abundant and renewable, the productionprocedure is simple, and the production costs are quite competitive. In thisresearch, experimental testing of the synergistic effects of new types inhibitor ieextract purple potato (Ipomoea batatas L.) which has the main content ofanthocyanin with commercial inhibitor-based amine (aniline) and with ascorbicacid inhibitors.The study aims to analyze the rate of corrosion and metal corrosioninhibition efficiency of steel (API 5L) in the produced water environment using amixed inhibitor purple sweet potato extract and commercial-based inhibitors ofamine (aniline). In addition, the corrosion rate analysis was also performed,inhibition efficiency, protection mechanisms and models of metal corrosioninhibition layer steel (API 5L) in the neighborhood of 3.5% NaCl using a mixedinhibitor purple sweet potato extract and ascorbic acid.Method of measuring the rate of corrosion and inhibition efficiency wasperformed using electrochemical polarization curves. Corrosion mechanismsinvestigated by Electrochemical Impedance Spectroscopy (EIS). To analyze themodel layer of inhibition were calculated using Fourier Transform Infra Red(FTIR) spectroscopy.The results showed that mixing purple sweetpotato extract has the abilityto synergistically with commercial inhibitor-based amine (aniline) in purplesweetpotato extract volume fraction of 25% with a yield of 82.14% inhibitionefficiency. For comparison, the same system using purple sweet potato extractonly produce inhibition efficiency of 68.30%, while the use of commercial-basedinhibitors of amine (aniline) alone resulted in inhibition efficiency of 74.88%.The addition of purple sweet potato extract volume of 1 mL to 4 mL intoascorbic acid inhibitors 10-4 M improving steel metal corrosion inhibitionefficiency (API 5L) in a solution of 3.5% NaCl of inhibition efficiency of 23.37%to 57.52%. The corrosion inhibitor mixture affect the anodic and cathodicpolarization curves so that it can act as a mixed inhibitor. Testing EIS shows thecorrosion process is controlled by the passivation mechanism indicated by anincrease in the surface resistance of corrosion.On the surface layer of a process of adsorption and formation of organochelates (flavonoids) in which the metal purple sweet potato extract with the maincontent of anthocyanins act as forming metal-chelated. Location of the chelatingligand purple sweet potato extract with the main content of anthocyanins occur inbond 3 ', 4' dihydroxy ring B or 3-Hydroxy 4-Carbonyl ring C.]"

"Pipa baja API 5L Grade B merupakan jenis pipa yang banyak dipakai pada struktur anjungan untuk minyak bumi dan gas, dan umumnya banyak digunakan sebagai pipa penyalur gas, air, dan minyak. Instalasi sistem perpipaan dengan menggunakan pipa baja API 5L Grade B terutama di zona air laut perlu mendapatkan perhatian khusus karena instalasi sistem perpipaan pada zona ini rawan terhadap masalah korosi terutama di lingkungan air laut. Kandungan terbesar pada logam paduan API 5L Grade B adalah unsur besi (Fe) sebanyak 98,06 % berat sehingga paduan ini tergolong dalam kelompok baja carbon rendah. Dan komposisi utama penyebab korosi pada paduan baja API 5L Grade B ini sangat didominasi unsur  carbon (C), oksigen (O), dan unsur chlor (Cl) yang ada di zona air laut dengan produk korosi adalah fasa FeCl₂ (lawrencite), FeO₂ (lepidocrosite), Fe₂O₃ (hematite), dan Fe₃O₄ (magnetite). Laju korosi tertinggi diperoleh pada sampel API 5L Grade B yang diletakkan di dalam lingkungan pantai yaitu sebesar 20.84 mpy pada saat pasang, sedangkan laju korosi tertinggi pada saat surut terjadi pada sampel API 5L Grade B yaitu sebesar 12.14 mpy yang diletakkan di lingkungan air payau. Bentuk korosi yang terjadi meliputi tiga tahapan korosi, yaitu pada awalnya terjadi korosi seragam yaitu suatu bentuk korosi elektrokimia yang terjadi dengan tingkat ekuivalen tinggi pada seluruh bagian permukaan yang diuji dan sering kali meninggalkan suatu kerak dibalik permukaan atau endapan. Kemudian dengan meningkatnya laju korosi dan factor lingkungan korosi menyerang daerah celah, sehingga terbentuk korosi celah (crevice corrosion) dibatasi hanya untuk serangan terhadap paduan-paduan yang oksidanya terpasifkan oleh ion-ion agresif seperti klorida dalam celah-celah atau daerah-daerah permukaan logam yang tersembunyi dan pada akhirnya membentuk korosi sumuran (pitting corrosion).

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Steel pipe of API 5L Grade B is a type of pipe that is widely used in bridge structures for oil and gas, and generally widely used as gas, water, and oil pipelines. Installation of piping systems using steel pipe API 5L Grade B, especially in sea water zone needs special attention because of the installation of the piping system in this zone is prone to corrosion problems, especially in the marine environment. The content of the metal alloy largest API 5L Grade B is the element iron (Fe) around 98.06 wt% so that the alloy is classified in the group of low carbon steel. And the composition of the main causes of corrosion in steel alloys API 5L Grade B is dominated elements carbon (C), oxygen (O), and chlorine (Cl) in the zone of sea water with corrosion products are phases of FeCl₂ (lawrencite), FeO₂ (lepidocrosite), Fe₂O₃ (hematite) and Fe₃O₄ (magnetite). The highest corrosion rate was obtained on a sample of API 5L Grade B is placed in the beach environment is equal to 20.84 mpy at high tide, while the highest corrosion rate at low tide occurs in samples of API 5L Grade B is equal to 12:14 mpy placed in brackish water environments. Form of corrosion that occurs includes three stages of corrosion, the first is uniform corrosion namely a form of electrochemical corrosion that occurs with high equivalent level in all parts of the surface are tested and often leave behind a surface crust or sediment. Then by increasing the rate of corrosion and the environment factor, the corrosion attacked gap area, thus forming a crevice corrosion (crevice corrosion) which limited only to attacks on the oxide alloys by aggressive ions such as chloride in the gaps or areas of the metal surface hidden and eventually form the pitting corrosion (pitting corrosion)."

"ABSTRAKKebutuhan akan sarana dan prasarana untuk memenuhi kebutuhan hidup yang memudahkan manusia untuk beraktivitas seperti jembatan, pelabuhan, rumah, jalan dan bangunan lainnya semakin diperlukan. Keseluruhan bangunan tersebut menggunakan konstruksi beton bertulang, yang kekuatannya ditentukan tidak hanya oleh mutu beton itu sendiri, tetapi juga dipengaruhi oleh kondisi fisik di sekitar bangunan tersebut. Pencemaran air, tanah dan udara di daerah Jakarta sudah semakin buruk, terutama pencemaran air laut akibat produksi limbah yang semakin meningkat. Kondisi tersebut akan mempengaruhi kekuatan struktur dan umur bangunan. Unsur kimia pada air laut yang tercemar tersebut secara teoritis mendukung terjadinya korosi pada tulangan beton bertulang. Penelitian ini bertujuan untuk membuktikan teori bahwa kemungkinan terjadinya korosi dipengaruhi oleh mutu beton; kecepatan korosi dipengaruhi oleh pencemaran air laut yang semakin tinggi di sekitar tulangan beton bertulang; dan semakin rendah mutu _tulangan beton, semakin cepat terjadinya korosi. Pembuktian hipotesa yang ada tersebut akan dibuktikan dengan menggunakan metode immersi dan metode polarisasi, yang sesuai dengan standar ASTM. Hasil yang diperoleh dengan penggunaan metode immersi menunjukkan bahwa laju korosi pada tulangan besi ST 41 yang dicelupkan selama 34 hari pada air bersih sebesar 7,62 mpy lebih cepat daripada tulangan besi ST 41 yang dicelupkan pada air laut dengan nilai 5,45 mpy. Sedangkan melalui penggunaan metode immersi menunjukkan bahwa laju korosi pada tulangan besi ST 60 yang dicelupkan selama 60 hari pada air bersih sebesar 5,15 mpy lebih cepat daripada tulangan besi ST 60 yang dicelupkan pada air laut dengan nilai 3,09 mpy. Sedangkan hasil yang ditunjukkan pada pengujian dengan menggunakan metode polarisasi yang dicelupkan pada air bersih, yaitu laju korosi pada tulangan besi ST 41 sebesar 2,039 lebih cepat dibandingkan dengan tulangan besi ST 60 yaitu 1,229 mpy. Dan hasil yang ditunjukkan pada pengujian dengan menggunakan metode polarisasi yang dicelupkan pada air laut, yaitu laju korosi pada tulangan besi ST 41 sebesar 7,482367 lebih cepat dibandingkan dengan tulangan besi ST 60 yaitu 3,876433 mpy.

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