Hasil Pencarian  ::  Simpan CSV :: Kembali

"Series of Ti2+-Mn4+ ions substituted BaFe12-2xTixMnxO19 samples with x = 0.0–0.8 have been studied to find out the effect of ion substitution on their microstructure, magnetic, and microwave absorption characteristics. The materials were synthesized through the mechanical alloying process. X-ray diffraction pattern for all sintered samples confirmed that the materials are single phase materials with BaFe12O19 structure. Referring to the results, it is shown that all samples that are subject to ultrasonic irradiation treatment characterized by a crystallite size distribution with the width get slimmer and mean crystallite size get smaller as the substitution level increased from x = 0 to x = 0.8. A sample of latter composition has fine crystals between 10–200 nm with the mean size of 42 nm. The effect of ionic substitution also affected the magnetic properties in which coercivity decreased proportionally with an increase of x value. The saturation magnetization increased to 0.41 T at x = 0.4, and then decreased for higher x values. Hence, the increase occurred only in samples with low-level substitutions of Ti2+-Mn4+ ions. Microwave absorption characterization clearly shows that the reflection loss (RL) value of Ti2+-Mn4+ substituted BaFe12-2xTixMnxO19 samples was enhanced from 2.5 dB in a doped free sample (x = 0) to 22 dB (~92% absorption) in a sample with x = 0.6 in the frequency range 8–12 GHz."

"Barium heksaferit disubtitusi Mn, Ba(Fe1-xMnx)12O19, telah diteliti dengan nilai x=0.00, 0.05, 0.10, 0.15, 0.20, 0.30, 0.40 dan 0.50. Sampel dipreparasi dengan metode solid state reaction dengan tahapan milling, kalsinasi dan sintering. Sampel dicampur dari bahan dasar BaCO3, Fe2O3 dan MnO2 kemudian dimilling selama 24 jam dengan atraitor ball mill. Hasil DTA didapatkan ada peak endotermik pada suhu 200°C, 300°C dan 600°C yang berhubungan dengan dehidrasi sampel, dekomposisi MnO2 dan pelepasan CO2 dari BaCO3. Sampel dikalsinasi pada suhu 1200°C selama 2 jam dengan kenaikan suhu 30C/menit. Hasil XRD setelah setelah kalsinasi menunjukkan bahwa tidak didapatkan lagi fase bahan dasar dan single phase. Hasil refinement dengan rietveld analysis didapatkan nilai parameter kisi a,b dan c. Sampel dikompaksi pada tekanan 5 MPa untuk sampel berbentuk ring dan 8MPa untuk sample berbentuk pellet pada medan magnet. Sampel disinterring pada suhu 1050°C, 1100°C, dan 1200°C selama 2 jam. Sebelum dicapai suhu sampel ditahan pada suhu 100°C, 300°C dan 600°C masing-masing selama setengah jam. Massa jenis sample diukur dengan metode Archimedes dan didapatkan bahwa massa jenis sample diatas 75% dari massa jenis teori (5.3 gram/cm3). Hasil pengukuran porositas didapatkan bahwa porositas dibawah 10%. Sample diukur sifat magnetiknya dengan permagraph. Didapatkan bahwa remanence dan energy produk berkurang ketika nilai x bertambah.

---

Barium Hexaferit doped Mn, Ba(Fe1-xMnx)12O19, have been investigated for x=0.00, 0.05, 0.10, 0.15, 0.20, 0.30, 0.40 and 0.50. The preparation is carried out by solid state reaction that corresponds to milling, calcinations and sintering. The precursor BaCO3, Fe2O3 and MnO2 were mixed and milled for 24 hours using attraitor ball mill. DTA results shown there were endothermic peak at 200°C, 300°C dan 600°C that corresponds to sample dehydration, decomposition of MnO2 and releasing of CO2 from BaCO3. Samples were calcined at 12000C for 2 hours with increment 30C/minute.

XRD result showed there were no precursor phase and single phase. Lattice parameter obtained through refinement rietveld analysis. Samples were pressed by 5 MPa for ring shaped and 8 MPa for pellet shaped in magnetic field. Sample were sinterred at 1050°C, 1100°C, and 1200°C for 2 hours.

Before reached the sintering temperature was hold at 100°C, 300°C and 600°C for a half hours each. Density was measured trough arhimedes method and obtained that density was more thant 75 % theoretical density (5.30 gram/cm3). Porosity measurement result were under 10%. The sample magnetic properties was measured using permagraph. The results showed that remanence and energy product decrease as x value increase."

"Strontium hexaferrite dengan komposisi nominal Sr0.6Fe,-<,..,jMn,TiyO, (x =0, y=; x = 0.4, y= 0.6; x = 0.5, y = 0.5; x = 0.6, y =0.4) disintesa dengan reaksi keadaan padat. Empat komponen serbnk BaCO,, SrCO,, Fe,O,, MnCO,, dan TiO, dicampur menggunakan High Energy Milling selama 10 jam dan disinterring pada 1050'C dalam tekanan atrnosfer selama 15 jam dan pendinginan eli tungku pemanas. X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), vibrating sample magnetometer (VSM) dan network analyzer digunakan untuk analisa struktur, sifat elektomagnetik dan penyerapan gelombang. Hasil memperlihatkan bahwa identifikasi fasa dengan penghalusan pola difrkasi XRD diperoleh fasa tunggal untuk substitusi Mn-Ti terhadap Sr0.6Fe,o, dengan x ~ y dan multi fasa terbentuk untnk x " y. Analsis mikrostrnktur dengan SEM menunjukkan variasi partikel adalah 2 - 5 um. Evaluasi terhadap karakteristik magnetik mengindikasikan bahwa terjadi penurunan koersifitas dengan kenaikan substitusi ion Mn2+ dan Ti4+ tetapi penurunan yang signifikan diperoleh terhadap saturasi magntetisasi pada substitusi Mn dan Ti dengan x :t: y. Penelitian saat ini menunjukkan penyerapan gelombang, reflection dan transmission dan juga reflection loss pada rentang frekuensi 7-16 GHz. Dilaporkan juga performansi penyerapan pada substitusi Mn dan Tipada strontium hexaferrite.

---

Strontium hexaferrite with nominal compositions Sr0.6Fe,-{"':Y~xTiy03 (x ~ 0, y o=Q; x ~ 0.4, y ~ 0.6; x ~ 0.5, y ~ 0.5; x ~0.6, y ~ 0.4) have been synthesized by solid state reaction. The four components powder were BaCO,, S!CO,, Fe,O,, MnCO,, and Ti02 mixed with High Energy Milling for 10 hours and sintered at I 050'C in the air at atmosphere pressure for 15 hour and furnace cooling. X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), resonance vibrating sample magnetometer (R· VSM) and vector network analyzer were used to analyze its structure, electromagnetic and microwave absorption properties. The result showed that, phase identification by refinement results ofXRD pattern confirmed single phase was obtained for Mn-Ti substituted Sr0.6Fe20, with x ~ y and multiphase formed for x" y. The microstructure analyses by SEM showed that the varied particle sizes of 2 -- 5 ~-tm. Evaluation on the magnetic characteristic indicated that coercivity decreased as the number ofMn2"~" and Ti +ions increased but significant decrease in saturation magnetization obtained for Mn and Ti substitution with x ::1:- y. Present investigation demonstrates that microwave absorber. reflection and transmission as well as reflection loss in the frequency range 7-16 GHz were derived Absorption performance ofMn and Ti substituted strontium hexaferrite are also reported."

"This paper reports on the magnetic properties and electromagnetic characterization of La0.8Ba0.2FexMn½(1-x)Ti½(1-x)O3 (x = 0.1–0.8). The La0.8Ba0.2FexMn½(1-x)Ti½(1-x)O3 (x = 0.1–0.8) materials were prepared using a mechanical alloying method. All the materials were made of analytical grade precursors of BaCO3, Fe2O3, MnCO3, TiO2, and La2O3, which were blended and mechanically milled in a planetary ball mill for 10h. The milled powders were compacted and subsequently sintered at 1000°C for 5h. All the sintered samples showed a fully crystalline structure, as confirmed using an X-ray diffractometer. It is shown that all samples consisted of LaMnO3 based as the major phase with the highest mass fraction up to 99% found in samples with x < 0.3. The mass fraction of main phase in doped samples decreased in samples with x > 0.3. The hysteresis loop derived from magnetic properties measurement confirmed the present of hard magnetic BaFe12O19 phase in all La0.8Ba0.2FexMn½(1-x)Ti½(1-x)O3 (x = 0.1–0.8) samples. The results of the electromagnetic wave absorption indicated that there were three absorption peaks of ~9 dB, ~8 dB, and ~23.5 dB, respectively, at respective frequencies of 9.9 GHz, 12.0 GHz, and 14.1 GHz. After calculations of reflection loss formula, the electromagnetic wave absorption was found to reach 95% at the highest peak frequency of 14.1 GHz with a sample thickness of around 1.5 mm. Thus, this study successfully synthesized a single phase of La0.8Ba0.2FexMn½(1-x)Ti½(1-x)O3 (x = 0.1–0.8) for the electromagnetic waves absorber material application."

"ABSTRAKFerrire banyak dikenal sebagai material yang digunakan untuk magnet permanen, maupun sebagai material magnet tidak permanen dan banyak digunakan dalam berbagai aplikasi seperti penyimpan data computer, perangkat gelombang radio, televisi hingga gelombang mikro. Disamping itu banyak digunakan sebagai Elektromagnetic Impedance (EMI) yang mampu melindungi sistem perangkat elektronik dari gangguan interferensi. Ferrite juga difungsikan sebagai material penyerap (absorbel) gelombang mikro untuk mereduksi radiasi pantul pada perangkat anti deteksi (slealth). Penelitian ini mengembangkan material hexaferrite tipe-M (Ba0.6Fe2O3) aebagai absorbing material melalui rekayasa struktur dengan metoda mekanika milling (mechanical alloying), khnsusnya substitusi secara parsial ion Fe dengan ion Mn dan ion Ti sehingga membentuk senyawn Ba06(Fe,Mn,Ti)2O3.Pembetukan fasa BaFe12-2x(MnTi)xO19 (X bervariasi dari 0.0 hingga 2,5) diperoleh melalui dua tahap, diawali dleh substitusi ion dan ion Titerhldap ion Fe dalam komponen material Fe;03 untuk membentuk fasa (Fe,Mn,Ti)203. Kemudian material hasil substitusi dipadukan secara mekanik dengan komponen BaC03 untuk membentuk fasa barium hexakrire tipe - M, setelah melalui reaksi padat. Hasil diuji dengan difraksii-aksi sinar X (XRD) untuk memastikan fasa material yang terbentuk. Obeservasi mikrostruktur material dilakukan baik dengan SEM maupun TEM untuk mengetahui ukuran dan morfologi kristal yang terbentuk. Perangkat permeagraph yang dilengkapi dengan medan magnet luar hingga 2,15 T digunakan untuk kajian sifat-sifat magnetik. Kajian terhadap karakteristik serapan gelombang elektromagnetik oleh material yang diteliti dilaksanakan melalui perangkat Network Analyser ( HP-8753ES) terutama pada jangkau frekuensi yang tersedia l GHz hingga 6 GHZ.Hasil XRD terhadap komponen material memastikan bahwa substitusi partial ion Fe+3 dengan ion Mn+2 dan Ti+4 dapat berjalan dengan baik yaitu pola difraksi Fe2O3 dapat dipertahankan pasca subsitusi parsial. Demikian jugad engan material BaFe12-2x(MnTi)xO19. Namun evaluasi parameter sel satuan menunjukkan terjadi pembahan parameter kisi fasa BaFe12-2x(MnTi)xO19 dari c = 23.2093 nm pada nilai konvensional BaFe12019 menjadi c = 22.8146 nm pada BaFe7(MnTi)2.5O19, sedangkan nilai parameter kisi a ccnderung konstan dengan kisaran 5.8839 nm (nilai konvensionalnya 5.8862 nm). Sebagai konsekuensi lain dari substitusi ion Mn dan ion Ti dalarn material BaFe12-2x(MnTi)xO19 adalah terjadinya peruhahan sifat magnetik terutama koersifitas yang bertambah rendah nilainya dengan bertambahnya fraksi ion Mn dan ion Ti. Dari hasil pengujian diperoleh bahwa koersivitas untuk x = 0 adalah 142 kA.m-1, turun 566313 signifikan menjadi 3 kA.m-1 pada x = 2,5.Magnetisasi total juga mengalami penurunan nilai karena berlcurangnya fiaksi ion Fe dalam BaFe12-2x(MnTi)xO19 dari ~ 0,38 T (untuk x= 0) menjadi ~ 0,21 T (untuk x = 2,5). Nilai koersivitas yang rendah, magnetisasi total yang tinggi serta resistivitas listrik yang besar adalah beberapa sifat yang dikehendaki oleh material untuk berperan sebagai material penyerap gelombang elektromagnetik.Serapang gelombang mikro pada material ferrite dengan 0< x < 2,0 dikarakteristikkan oleh serapan pada dua daerah frekuensi dengan jangkau frekuensi yang cukup lebar. Serapan pertama terjadi pada jangkau frekuensi ~ 1250 MHZ sampai dengan - 2750 MHZ. Pada jangkau frekuensi ini material (tidak termasuk untuk x = 0) memperlihatkan fraksi serapan yang hampir sama mencapai nilai - 40 dB. Daerah frekuensi serapan kedua terjadi pada jangkau frekuensi ~2750 MI-Iz sampai dengan 5000 MHz. Dalam jangkau frekuensi ini ketiga jenis material memiliki karakteristik berbeda. Dengan meningkatnya reaksi ion subsitusi jangkau frekuensi serapan diperlebar meskipun terjadi penurunan nilai reflection loss. Pada material dengan frakksi ion substitusi x = 2,5 terjadi pergeseran frekuensi serapan pada jangkau frekuensi serapam pertama disertai dengan peningkatan pelebaran jangkau frekuensi.Sebagai kesimpulan, Karakteristik electromagnetic wave absorber material BaFe12-2x(MnTi)xO19 memiliki frekuensi serapan dengan rentang frekuensi yang lebar pada daerah frekuensi l - 6 GHz. Pada rentang frekuensi tersebut terjadi serapan gelombang pada dua frekuensi berbeda yaitu pada - 2000 MHz dan ~ 3500 MHz dengan faktor penurunan koefisien refleksi (reflection loss) yang relatif rendah mencapai - 30 sampai dengan - 40 dB. Rentang frekuensi sempat meningkat dengan meningkatnya fraksi ion substitusi Ti dan Mn. Nanostruktur material ikut dalam pelebaran frekuensi serapan gelombang elektromagnetik.

---

ABSTRACTFerrite was widely known for a material used for permanent magnet as well as for non-permanent magnet. It was also widely used in various applications such as in media storage, computers, radio frequency components televisions and even in microwaves. In addition to that, it was also used as an Electromagnetic impedance (EMI), which was able to protect electronic components from interference. Ferrite was also used as the material to absorb microwaves to reduce a reflective radiation in devices with stealth capabilities. This research was intended to develop hexaferrite material (Ba0 6Fe203) as an absorbing material through structural engineering with mechanical milling (mechanical alloying) method, specifically 'through partial substitution of Fe ion with nm and Ti ions to form the Ba06(Fe,Mn,Ti)2O3 compound.The formation of BaFe12-2x(MnTi)xO19 phase (x varied from 0.0 to 2.5) was obtained through two stages, beginning with the substitution of the Fe ion with Mn and Ti ions in the material component of Fe2O3 to form the (Fe,Mn,Ti)203 phase. Next, the result of this substitution was combined mechanically with BaC03 component to form the Type-M barium hexaferrite phase, after undergoing a solid reaction. The result of this synthesis was tested using X Ray Diffraction (XRD) to the formed phase- material. The material?s structural observation was done with SEM as well as TEM to ascertain the dimension and morphology of the formed crystals. The Permeagraph device, which was equipped with external magnetic field up to 2.15 T, was used to study the magnetic characteristics. The study on the characteristic of the electromagnetic wave absorption was done utilizing the Network Analyzer (HP-8753ES) particularly within the available frequency range from I GHz to 6 GHZ.The result of the XRD of the component material synthesis showed that the partial substitution of Fe ion with Mn+2 and Ti? ions had gone well as in the diffraction pattern of Fe;O3 which had been maintained after the partial substitution. Likewise the BaFe12-2x(MnTi)xO19 . However, an evaluation of the cell unit parameter showed a change in the grid parameter of the BaFe12-2x(MnTi)xO19 phase in BaFe|1O|9 conventional value from c=23.2093 nm to c=22.8!46 nm in BaFe1(MnTi);50|g meanwhile the grid of a parameter value tend to be constant at the range of 5.8839 mn (the conventional value being 5.8862 nm). Another consequence of the substitution of Mn and Ti ions in BaFe12-2x(MnTi)xO19 was the change in magnetic characteristic specifically in the lowering of the coervicity with the increase of the Mn and Ti ions fractions. Test result showed that the coercivity for x=0 was 142 kA.m-1 decreased drastically to 3 kA.m-1 for x=2.5. The total of magnetizing was also decreased in value due to the reduced Fe ion fraction in BaFe12-2x(MnTi)xO19 from -0.38 T (for x=0) to ~0.2l T (for x=2.5). The low coercivity , high magnetizing and high resistivity to electricity are amongst the desired characteristics in a material so B to be useful as an electromagnetic wave absorber.Microwave absorption in ferrite material with 0