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"Studi Kinetika reaksi hidrogenasi C02 menjadi metanol dengan basis katalis oksida Iogam Cu da.n campuran lainnya sudah banyak dilakukan oleh para peneliti sebelumnya. Keanekaragaman Percobaan yang telah dilakukan menghasilkan berbagai jenis mekanisme reaksi dan persamaan kinetika yang bervariasi. Pada penelitian kali ini katalis yang digunakan adalah CuO/Zn0/A1103/Cr1O3 dengan luas permukaan katalis sebesar 25 m2/gr. Untuk mencegah terjadinya difusi intemal dan difusi ekstemal pada pengambilan data kinetika, maka dilakukan percobaan pendahuluan menggunakan diameter katalis berkisar antara 0,125 - 0,25 mm dan laju alir umpan di atas 100 ml/menit. Penentuan persarnaan laju reaksi dilakukan dengan analisis kinetika adsorpsi isotermal berdasarkan asumsi mekanisme reaksi Coterorzm, sehingga diperoleh persamaan laju pembentukkan metanol adalah sebagai berikut : rM = (0,3075)Pco2Ph2 / 1 + 0.5516Pco2 - 1,18417Pco2Ph2"

"The construction and excitation circuit of carbon dioxide laser 616 mm long is described. The dependence of the pulse emission energy on the energy supplied to the discharge, the pressure and composhdon gaseous mixture is presented. The emission energy is 1-2 Joules. The emission pulse isexpected to cover range from 100 ns - 200 ns."

"The carbon dioxide laser is one of the most versatile types on the marked today. It emits infrared radiation between 9 and 11 micrometer (μm) either at a single line selected by the user or on the strongest line in untuned cavities. It can produce continuous output power output powers ranging from well under 1W for scientific applications to many kilowatts for material working. It can generate pulses from the nanosecond to millisecond regimes. Custom made CO2 lasers have produced continues beams of hundreds of kilowatts for military laser weapon research (Hecht 1984) or nanosecond long pulses of 40 kilo joules (kj) for research in laser induced nuclear fusion (Los Alamos National Laboratory 1982). This versatility comes from the fact that there are several distinct types of carbon dioxide lasers. While they share the same active medium, they have important differences in internal structure and more important to the user in lunch oral characteristic. In theory the structural variations could range over a really continuous spectrum, but manufactures have settled on a few standard configurations which meet most user needs. This users see several distinct types, such as waveguide, low power sealed tube, high power following gas, and pulsed transversely excited CO2 lasers. On TEA lasers discharge instabilities make continuous wave operation impractical at gas pressures above about 100 torr (13,3 MPa). How everit is possible to produce pulses lasting tens of nanosecond to microseconds. Such lasers are called transversely excited atmospheric (TEA) lasers because they operate at or near atmospheric pressure, although same times the term is applied to pulsed transversely excited CO2 lasers which operate at higher or lower pressures. The TEA lasers prime attraction of high power per unit volume of laser gas and have fairly complex power requirements because of the nature of their pulsed operation. Typically same energy in the form of electrons or ultraviolet photons is discharged into the laser gas slightly before the main pulse to make it possible to obtain higher output power. In this thesis, basic theory of the Carbon dioxide laser are presented in section II. Section III descibe Optical Transducer. Section IV contains the characterization of carbon dioxide laser with the results and graphs. Finally some conclusion regarding our discussion are summarized in section V."

"Elektroreduksi CO2 merupakan teknik yang menjanjikan karena dapat mengkonversi CO2 secara langsung menjadi hidrokarbon. Penggunaan elektroda Cu dan boron-doped diamond (BDD) dalam proses elektroreduksi CO2 dilaporkan mampu menghasilkan konversi CO2 menjadi turunan hidrokarbon secara efisien. Pada penelitian ini, deposisi Cu2O ke permukaan BDD dan Cu dilakukan guna meningkatkan sifat katalitik BDD, sekaligus mempelajari jenis spesi Cu yang paling berperan dalam reaksi elektroreduksi CO2. Deposisi elektroda dilakukan dengan menggunakan teknik amperometri. Pada setiap elektroda dilakukan karakterisasi dengan menggunakan instrumentasi Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS), X-Ray Photoelectron Spectroscopy, dan Cyclic Voltammetry (CV). Elektroreduksi dilakukan dalam sistem dua  kompartemen berbentuk H dengan menggunakan larutan NaCl 0.1 M yang ditempatkan di katoda serta Na2SO40.1 M ditempatkan di anoda. Elektroreduksi dilakukan dengan menggunakan sistem kerja tiga elektroda yang terdiri dari elektroda kerja, elektroda pendukung berupa kawat Pt, serta elektroda pembanding Ag/AgCl pada variasi potensial -1.0 V dan -1.5 V selama 60 menit. Produk hasil reduksi dianalisa dengan menggunakan High Performance Liquid Chromatograph (HPLC) dan Gas Chromatography (GC) untuk produk liquid serta untuk untuk produk gas menggunakan Gas Chromatography (GC) dengan detektor TCD. Elektroda Cu2O-BDD menghasilkan produk yang paling bervariasi dibandingkan dengan elektroda lainnya dengan produk hasil berupa asam format, etanol, dan asam asetat. Produk dengan jumlah  paling banyak dihasilkan adalah asam asetat dengan jumlah 29,8 mg/L dengan persen (%) efisiensi faraday sebesar 68,2  % oleh elektroda Cu2O-BDD pada potensial -1.5 V.

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CO2 Electroreduction is a promising technique in CO2 reduction because it can converts CO2 directly into hydrocarbon. The uses of Cu and Boron-Doped Diamond as working electrode in CO2 electroreduction is reported to be able converting CO2 into hydrocarbon derivative efficiently. In this research, Cu2O deposited into BDD and Cu surfaces to increase the BDD catalytic activity and study which Cu has the biggest role in electroreduction CO2 process. Deposition of the material into electrode surface is done using amperometry technique. Each electrode characterized using Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), and X-Ray Photoelectron Spectroscopy, and Cyclic Voltammetry (CV) instrumentation. Electroreduction process is done using  two compartment system with H-shaped using NaCl solution 0.1 M in cathode and Na2SO4 in anode. Electroreduction performed using three electrode system, which are working electrode, Pt mesh as counter electrode, and Ag/AgCl as reference electrode with -1,0 V and -1,5 V potential in 60 minutes. The resulting product is analyzed using High Performance Liquid Chromatograph (HPLC) and Gas Chromatography (GC) for liquid product and GC with TCD detector for the gas product. The reduction process using Cu2O-BDD as working electrode produced more variative products other than the other electrodes, which are formic acid, ethanol, and acetic acid. The most produced product from the process is acetic acid with in concentration 29,8 mg/L and %faradaic efficiency 68,2% using Cu2O-BDD electrode in -1,5 V potential."

"Many applications and industrial processes require very low cooling temperature, such as cold storage in the biomedicalfield, requiring temperature below -80 °C. However, single-cycle refrigeration systems can only achieve the effectivecooling temperature of -40 °C and, also, the performance of the cycle will decrease drastically for cooling temperatureslower than -35°C. Currently, most of cascade refrigeration systems use refrigerants that have ozone depletion potential(ODP) and global warming potential (GWP), therefore, in this study, a cascade system is simulated using a mixture ofenvironmentally friendly refrigerants, namely, carbon dioxide and a hydrocarbon (propane, ethane or ethylene) as therefrigerant of the low temperature circuit. A thermodynamic analysis is performed to determine the optimal compositionof the mixture of carbon dioxide and hydrocarbons in the scope of certain operating parameters. In addition, aneconomic analysis was also performed to determine the annual cost to be incurred from the cascade refrigeration system.The multi-objective/thermoeconomic optimization points out optimal operating parameter values of the system, toaddressing both exergy efficiency and its relation to the costs to be incurred."