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Abstrak :
80% kegagalan material baja pada fasilitas produksi industri minyak dan gas bumi disebabkan oleh proses korosi. Salah satu pengendalian proses korosi material baja API 5L Grade X60 dengan menggunakan inhibitor ramah lingkungan. Pada penelitian ini, ekstrak kayu secang (Caesalpinia Sappan L.) dievaluasi sebagai inhibitor ramah lingkungan untuk baja API 5L X60 di lingkugan HCl 1M dengan variasi volume ekstrak 0,5 ml, 1 ml, 1,5 ml, 2 ml, 3ml dan variasi temperatur 302K, 312K, 322K, dan 332K menggunakan metode polarisasi tafel, Electrochemical Impedance Spectroscopy (EIS), Fourier Transform Infra-red Spectroscopy (FTIR), dan Stimultaneous Thermal Analysis (STA). Hasil dari pengujian polarisasi tafel dan EIS menunjukan ekstrak kayu secang bertindak sebagai inhibitor campuran (Mixed Inhibitor). Efisiensi optimal dihasilkan dari penambahan volume ekstrak sebesar 1,5 ml dalam 400 ml HCl 1M. sebesar 91 % polarisasi tafel, dan sebesar 94% EIS. Rapat arus korosi material pada volume 1,5 ml ekstrak kayu secang sebesar 57 µA/cm2 dan nilai resistivitas larutan 841 ?.cm2. Kenaikan temperatur lingkungan sebesar 332 K menaikan rapat arus korosi material menjadi 139 µA/cm2 dan menurunkan nilai resistivitas larutan sampai 121 ?.cm2, sehingga nilai efisiensi inhibitor turun sampai 50%. Gugus fungsi keton (C=O) muncul dari hasil karakterisasi pengujian FTIR yang menandakan keberadaan senyawa brazilein dan dan sappanchalcone. ......80 % failure of carbon steel at oil and gas production facility was caused by corrosion. One of corrosion mitigation of carbon steel was used green inhibitor. In this study, Caesalpinia Sappan L. extract has been evaluated as green inhibitor corrosion for API 5L X60 in HCl 1M environment with variation of volume extract 0,5 ml, 1ml, 1,5 ml, 2ml, 3ml and variation of temperature 302K, 312K, 322K, and 332K using Tafel polarization and Electrochemical Impedance Spectroscopy (EIS), Fourier Transform Infra-red Spectroscopy (FTIR), dan Stimultaneous Thermal Analysis (STA).The Result show the tafel polarization and EIS show caesalpinia sappan extract acts for inhibit corrosion process in the system with mixed type inhibitor. Optimal inhibiton efficiency occurs at volume 1.5 ml extract caesalpinnia sappan/400 ml HCl 1M, 91% for tafel polarization and 94% for EIS. Current density at volume extract 1,5 ml was 57 µA/cm2 and resistivity of solution 841 ?.cm2. Increasing temperatur of environment will increase current density to 139 µA/cm2 and decrease resistivity to 121 ?.cm2. So, the inhibition efficiency decrease to 50%. Keton fuctional group was found showed exisstance of showed that brazilein dan dan sappanchalcone

Abstrak :
ABSTRAK
Dewasa ini, material komposit banyak digunakan dalam berbagai aplikasi karena memiliki sifat mekanik yang lebih bagus dari pada logam, memiliki kekuatan pembentukan yang tinggi, memiliki ketahanan yang baik, memiliki kekuatan jenis dan kekakuan jenis (modulus Young) yang lebih tinggi daripada logam. Namun demikian, material komposit rentan terhadap degradasi termal pada temperatur tinggi. Oleh karena itu, penelitian dalam tesis ini bertujuan untuk meningkatkan ketahan termal dan sifat mampu bakar material komposit dengan mencampurkan zat tahan api berbasis halogen jenis brominated bisphenol A ke dalam material komposit serat karbon dengan dua variasi densitas serat, yaitu 200 dan 240 gr/m2. Penelitian yang dilakukan berbasis pada eksperimen skala laboratorium menggunakan kalorimeter kerucut. Fenomena pembakaran yang terjadi adalah piloted ignition dengan fluks kalor pembakaran dibatasi sampai dengan 25 kW/m2. Hasil penelitian menunjukkan bahwa sampel komposit serat karbon terbakar karena vaporisasi dari resinnya, sedangkan serat karbonnya sendiri hanya mengalami pengarangan (charring). Eksperimen pada fluks kalor 21,12 kW/m2, menunjukkan bahwa kebeadaan kandungan brominated bisphenol A di dalam sampel komposit serat karbon mampu menekan puncak laju produksi kalor dari sekitar 125 kW/m2 menjadi hanya sekitar 80 kW/m2. Hasil penelitian juga menunjukkan bahwa kandungan zat tahan api (fire retardant) mampu menunda waktu penyalaan api pembakaran dan memberikan ketahana termal yang lebih baik kepada material komposit

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ABSTRACT
Nowadays, carbon fiber reinforced epoxy-acrylate composite (CFRE) is used in various applications such as in aircraft and industrial applications including pressure vessels, civil engineering/construction-related uses, ship manufacturing, and automobile. That is because of its characteristics such as lightweight and high-strength. Nevertheless CFRE is very easy to be burned after preheating in a low heat flux, moreover with the presence of an external energy source. Hence, this study aimed to find out the effects of brominated bisphenol A as fire retardant agent on fire retardancy of CFRE using cone calorimeter with a spark igniter as a trigger to represent an amount of external energy source. Carbon fibers used in this study have density of 200 gr/m2 and 240 gr/m2. The parameter studied in this research includes density of carbon fiber, time to ignition, heat release rate and density of smoke production. In this initial work, the heat flux was limited up to 25 kW/m2 with piloted ignition. The measured temperatures of CFRE’s ignition range from 450oC to 575oC at atmospheric pressure. The initial result shows that the ignition of CFRE is strongly depend on the density of carbon fiber, the existing of an external energy source and the condition of gas mixture. For the density of of 200 gr/m2, CFRE starts to ignite under heat flux of 14.2 kW/m2 with peak heat release rate of 163.4 kW/m2. While for the density of of 240 gr/m2, CFRE starts to ignite under heat flux of 16.7 kW/m2 with peak heat release rate of 98 kW/m2. Combustion mechanism of CFRE started when a spark igniter is turned on after preheating at a certain sufficient heat flux, causing a flaming condition on the surface of CFRE. Next, vaporization of its resin causing a sustain flaming condition until reaching a decay period. When it burned, the resin vapor is forced out of the fiber pores, causing the material to swell and increased its volume. The effects of brominated bisphenol A as fire retardant agent in the CFRE give a significant impact to fire retardancy of the CFRE, especially in time to ignition and heat release rate aspect.

Abstrak :
This book contains manuscripts of topics related to numerical modeling in Civil Engineering (Volume 1) as part of the proceedings of the 1st International Conference on Numerical Modeling in Engineering (NME 2018), which was held in the city of Ghent, Belgium. The overall objective of the conference is to bring together international scientists and engineers in academia and industry in fields related to advanced numerical techniques, such as FEM, BEM, IGA, etc., and their applications to a wide range of engineering disciplines. This volume covers industrial engineering applications of numerical simulations to Civil Engineering, including: Bridges and dams, Cyclic loading, Fluid dynamics, Structural mechanics, Geotechnical engineering, Thermal analysis, Reinforced concrete structures, Steel structures, Composite structures.