Molecular conformation and organic photochemistry : time-resolved photoionization studies
Rasmus Y. Brogaard (Springer, 2012)
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Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecule relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics. |
Molecular Conformation and Organic Photochemistry.pdf :: Unduh
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No. Panggil : | e20405936 |
Entri utama-Nama orang : | |
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Penerbitan : | Berlin: Springer, 2012 |
Sumber Pengatalogan: | LibUI eng rda |
Tipe Konten: | text |
Tipe Media: | computer |
Tipe Pembawa: | online resource |
Deskripsi Fisik: | |
Tautan: | http://link.springer.com/book/10.1007%2F978-3-642-29381-8 |
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No. Panggil | No. Barkod | Ketersediaan |
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e20405936 | TERSEDIA |
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