Fluorescence properties of microcomposites europium triethylene glycol picrate complex doped in polymer
Dewi Tristantini, Slamet , Virleenda M. Setianingrum, Yoki Yulizar (Faculty of Engineering, Universitas Indonesia, 2014)
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The aim of this study was to synthesize high luminescence materials containing the optimal combination of ternary europiumpicrate complex and matrices. The ternary europium-picrate-triethylene glycol (Eu-EO3-Pic) complex was doped in poly(methyl methacrylate), PMMA. The composites were impregnated in several matrices to form thin filmsvia spin coating technique. The microparticles of Eu-EO3-Piccomplex were prepared by reprecipitation-evaporation, then they were compared to analogous complex or microcomposite prepared by in-situ method. The Eu-EO3-Pic/PMMA microcomposites were characterized by fluorescence spectroscopy in acetone solution. The particle sizes distribution of microcomposites synthesized by reprecipitation-evaporation method (110.3 to 426.8 nm) were smaller compared to the microcomposites by in-situ method (641.7 nm). The PMMA was able to significantly enhance the fluorescence intensity of Eu-EO3-Pic microparticles. The fluorescence intensity of microcomposite by in situ-preparation was lower than that found in the microcomposites by reprecipitation-evaporation method. We also investigated the effect of different matrices on the photophysical properties. The effective intermolecular energy transfer from PMMA to the Eu-EO3-Pic complex would produce high sensitization efficiency. These microcomposites are very potential used as the emission material for organic light emitting devices. |
No. Panggil : | UI-IJTECH 5:1 (2014) |
Entri utama-Nama orang : | |
Subjek : | |
Penerbitan : | Depok: Faculty of Engineering, Universitas Indonesia, 2014 |
Sumber Pengatalogan : | LibUI eng rda |
ISSN : | 20869614 |
Majalah/Jurnal : | International Journal of Technology |
Volume : | Vol. 5, No. 1, January 2014: Hal. 70-78 |
Tipe Konten : | text |
Tipe Media : | unmediated |
Tipe Carrier : | volume |
Akses Elektronik : | https://doi.org/10.14716/ijtech.v5i1.155 |
Institusi Pemilik : | Universitas Indonesia |
Lokasi : | Perpustakaan UI, Lantai 4 R. Koleksi Jurnal |
No. Panggil | No. Barkod | Ketersediaan |
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UI-IJTECH 5:1 (2014) | 08-23-33020472 | TERSEDIA |
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