Dimethyl 9-octadecenedioate and 9-oktadecene from methyl oleate via a ruthenium-catalyzed homo olefin metathesis reaction
Ilham Putra, Didin Mujahidin (Faculty of Engineering, Universitas Indonesia, 2017)
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| Oleic acid, one of the major components of palm oil, has attracted much interest in modern oleochemistry. The internal olefin group in oleic acid is a useful functional group in the transformation of a fatty acid to other functional chemicals and materials. In this paper, we discuss the application of the olefin metathesis reaction by preparing a long-chain dicarboxylic acid and alkene from the ester of oleic acid. The internal olefin metathesis reaction of methyl oleate produced dimethyl 9-oktadecendioate and 9-octadecene in the presence of a ruthenium Grubbs II (second generation) catalyst with a 51% yield. We also found that there was a higher amount of the E isomer products than the Z isomer products. |
| No. Panggil : | UI-IJTECH 8:8 (2017) |
| Entri utama-Nama orang : | |
| Subjek : | |
| Penerbitan : | Depok: Faculty of Engineering, Universitas Indonesia, 2017 |
| Sumber Pengatalogan : | LibUI eng rda |
| ISSN : | 20869614 |
| Majalah/Jurnal : | International Journal of Technology |
| Volume : | Vol. 8, No. 8, December 2017: Hal. 1422-1428 |
| Tipe Konten : | text |
| Tipe Media : | unmediated |
| Tipe Carrier : | volume |
| Akses Elektronik : | https://doi.org/10.14716/ijtech.v8i8.772 |
| Institusi Pemilik : | Universitas Indonesia |
| Lokasi : | Perpustakaan UI, Lantai 4 R. Koleksi Jurnal |
| No. Panggil | No. Barkod | Ketersediaan |
|---|---|---|
| UI-IJTECH 8:8 (2017) | 08-23-35285163 | TERSEDIA |
| Ulasan: |
| Tidak ada ulasan pada koleksi ini: 9999920530824 |
