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"The abality of light expanded clay aggregate to remove lead and cadmium from paint industry's effluents was studied at different levels of adsorbent, contact time and pH in April 2008...."

"Lead smelting produces pure lead from both primary and secondary lead minerals. Two types of produced emissions are fumes and lead oxide with very small particle size while larger particles are only generated in the preparation stages such as crushing and grinding. Gas emission from lead smelting with high lead content endanger environment. Plants, animals, and human health may be affected due to their toxic properties. It is necessary to control the lead emission from lead smelting operation by both setting ambient air quality standard which is designed to limit the emission and using high efficiency particulate control devices such as fabric filters and electrostatic precipitator"

"Metal contaminated soils are a major problem in Thailand. Plants that grow in this area will adsorb metal and broad impact across the food chain. Some types of biochar can immobilize metals and reduce the impact of such. This research was limited to study cadmium, zinc and lead adsorption. Durian and mangosteen shell were selected to produce biochar due to their high carbon content. The shells were firstly passed through the pyrolysis process. The chemical characterization of these biochars was then determined. The chemical characteristics of both materials were similar. Both were basic materials with pH around 10. They were high in percentage of C and TOC. Total Cd, Pb and Zn in both biochars were below the maximum allowed threshold according to biochar toxicity standard recommended by International Biochar Initiative. The buffering capability and acid neutralization capability were examined by adding acid and basic solution until the pH reached 2-12. The buffering capability of these two biochars was rather high. The values of acid neutralization capability (ANC) of biochar produced from durian and mangosteen shell were 1,464.80 meg/kg and 1,328.98 meq/kg, respectively. The study included an adsorption isotherm. Freundlich isotherm was a suitable isotherm to explain the adsorption of all three metals by biochar from durian shell, whereas Langmuir isotherm is better to explain the adsorption of metals by biochar from mangosteen shell. The adsorption capacity of both biochars was not much different."

"Peningkatan jumlah penduduk menyebabkan berkurangnya Ruang Terbuka Hijau RTH karena lahan dialihfungsikan untuk memenuhi kebutuhan manusia, akibatnya terjadi peningkatan volume air limpasan yang menggenang. Genangan air limpasan ini mengandung polutan yang berbahaya sehingga memerlukan adanya pengelolaan. Tujuan dari penelitian ini adalah mengurangi konsentrasi polutan logam pada air limpasan dengan teknologi sistem bioretensi. Digunakan tiga reaktor yang diisi dengan komposisi media berupa pasir kuarsa 60, tanah 20, dan kompos 20. Ketiga reaktor ini mewakili variasi usia tanaman Reaktor I dan II, yaitu 4 dan 6 bulan serta variasi jenis tanaman Reaktor II dan III, yaitu 1 dan 2 jenis tanaman. Tanaman yang digunakan adalah Iris pseudacorus dan Chrysopogon zizanioides L. Roberty. Air limpasan sintetis yang digunakan berada pada rentang konsentrasi antara 0.04-0.11 ppm, baik untuk logam Pb maupun Zn. Pengaliran air limpasan sintetis dilakukan sebanyak 6 kali dengan debit sebesar 2.75 L/menit. Hasil menunjukkan bahwa kondisi optimal penurunan konsentrasi kedua jenis logam terjadi pada reaktor II berisi 2 jenis tanaman berusia 6 bulan, dengan efisiensi sebesar 83.3 untuk logam Pb dan 98.3 untuk logam Zn. Reaktor bioretensi dengan 2 jenis tanaman berusia 6 bulan lebih signifikan dalam mengurangi konsentrasi logam pada air limpasan.

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Population growth can reduce Green Open Space since the land is converted to fulfill human needs, as a results the volume of water runoff increased. This water contains harmful pollutants that need to manage. The purpose of this study is to reduce metal pollutants in water runoff by bioretention technology. Three reactors were filled with media composition in the form of quartz sand 60, soil 20, and compost 20. Those reactors represent the variation of plant age Reactor I and II, ie 4 and 6 months and variation of plant species Reactor II and III, ie 1 and 2 plant species. The plants species are Iris pseudacorus and Chrysopogon zizanioides L. Roberty. Concentration range of synthetic runoff water is between 0.04-0.11 ppm, both for Pb and Zn metals. Synthetic runoff drainage was conducted 6 times with discharge of 2.75 L min. The results showed that the optimum condition of concentration reduction for both metals occurred in reactor II 2 types of plants aged 6 months, with efficiency of 83.3 for Pb and 98.3 for Zn. Bioretention reactor with 2 types of plants aged 6 months is more significant in reducing metal concentration in runoff water."

"State of Charge (SoC) baterai merupakan parameter yang digunakan untuk mengetahui keadaan isi baterai, dan dijadikan pedoman untuk memantau kapasitas terkini dari baterai. Estimasi nilai SoC menjadi sulit dilakukan karena adanya ketidaklinieran dalam reaksi kimia baterai ditambah SoC tidak dapat diukur secara langsung. SoC dapat diperoleh melalui nilai resistansi internal baterai yang saling berkorelasi sesuai dengan besaran tegangan terminal dan tegangan open circuit yang terjadi karena adanya arus baik saat proses charging maupun discharging. Modifikasi metode coulomb counting dalam memperoleh nilai resitansi internal adalah mudah dilakukan melalui pendekatan persamaan yang didapatkan melalui interpolasi dari data hasil eksperimen. Metode ini berhasil mendapatkan korelasi antara nilai SoC terhadap resistansi internal untuk dua keadaan yaitu charging dan discharging. Proses estimasi nilai SoC, dilakukan dengan cara mengestimasi nilai SoC saat terjadinya efek recovery untuk mendapatkan nilai maksimum/minimumnya selama periode tertentu.Metode yang dikembangkan berhasil mengestimasi nilai SoC bateri dengan pengukuran secara tidak langsung melalui resistan dalam baterai di saat proses charging atau discharging.

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Battery State of Charge (SoC) is a parameter used to determine the state of charge battery, and is used as a guideline for monitoring the current capacity of the battery. Estimating the value of SoC becomes difficult because of the nonlinearity in the reaction battery chemistry plus SoC cannot be measured directly. SoC can be obtained through the value of the internal resistance of the battery which is correlated according to the magnitude of the terminal voltage and the open circuit voltage that occurs due to the battery current both during the charging and discharging process. Modification of the coulomb counting method in obtaining internal resistance values ​​is easily done through the equation approach obtained through interpolation of experimental data. This method succeeded in obtaining a correlation between the SoC value and the internal resistance for two conditions, namely charging and discharging. Estimating the SoC value, by looking at the initial SoC value when the effect recovery occurs to get the maximum/minimum value for a certain period. The method developed has succeeded in estimating the SoC value of a battery by indirectly measuring the resistance in the battery during the charging or discharging process"

"Bentonit alam Jambi telah berhasil dimodifikasi menjadi Organoclay melalui proses interkalasi dengan senyawa asam amino Alanin. Sebelum dilakukan sintesis Organoclay, dilakukan proses fraksinasi dan sedimentasi dari bentonit alam Jambi yang bertujuan untuk mendapatkan bentonit yang kaya akan montmorillonite (MMT) dan menghilangkan pengotor yang terkandung di dalam bentonit. Kemudian dilakukan penyeragaman kation bebasnya dengan Na+ menjadi Na- Bentonit. Selanjutnya dengan menggunakan larutan tembaga amin, dilakukan penghitungan nilai Kapasitas Tukar Kation (KTK) dan diperoleh nilai KTK sebesar 35,3 mek/100 gram bentonit. Sintesis Organoclay kemudian dilakukan dengan menginterkalasikan senyawa Alanin ke dalam Na- MMT dengan 2 nilai KTK pada 3 kondisi pH, yaitu pH 4,7, pH isoelektrik Alanin (pH 6), dan pH 7. Hasil dari karakterisasi FTIR menunjukkan bahwa senyawa asam amino Alanin telah berhasil diinterkalasi ke dalam bentonit alam Jambi pada pH isoelektrik dengan munculnya serapan baru pada bilangan gelombang yang berbeda dengan Na- MMT. Organoclay yang telah disintesis kemudian digunakan sebagai adsorben ion logam berat kadmium dan timbal dengan proses optimasi waktu dan konsentrasi adsorpsi. Hasil menunjukkan bahwa Organoclay memiliki daya adsorpsi yang lebih besar terhadap logam berat dibandingkan dengan bentonit alam. Variasi pH interkalasi 4,7 dan 7 menghasilkan Organoclay dengan kemampuan adsorpsi yang lebih rendah dibandingkan Organoclay yang di interkalasi pada pH isoelektrik Alanin.

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Natural Jambi bentonite have been successfully modified into Organoclay through the intercalation process with acid amino compound Alanine. Before the process for the synthesis of Organoclay begins, the process of sedimentation and fractionation conducted on natural Jambi bentonite in order to get the rich inmontmorillonite (MMT) bentonite and removed the contaminer contained in the bentonite. Then the equalization of free cations is done with Na+ (called Nabentonite). Next, using a solution of copper amine, its cation exchange capacity (CEC) determined and the value of CEC acquired was 35,3 meq/100 grams of bentonite. Synthesis of Organoclay then performed by intercalating Alanine into Na-MMT with 2 values of CEC on 3 pH conditions i.e. pH 4,7, the isoelectric pH of Alanine (pH 6), and the pH 7.

The results of the characterization with FTIR indicated that acid amino Alanine compounds has managed to be intercalated into natural Jambi bentonite with the appearance of new absorbance at different wave number from Na- MMT. Organoclay which have been synthesized then used as an adsorbent of heavy metal ions cadmium and lead with the optimization of adsorption time and concentration process.

The results show that Organoclay have better adsorption capacity compared to unmodified natural Jambi bentonite against heavy metal ions. Organoclay synthesized in variated pH conditions (4,7 dan 7) have lower adsorption capacity than the Organoclay that synthesized in isoelectric pH of Alanine."

"Organoclay Jambi merupakan hasil modifikasi montmorillonite (MMT) dengan interkalasi kation organik agar dapat menjadi organofilik. Sebelum digunakan untuk preparasi, proses yang pertama adalah fraksinasi terhadap bentonit Jambi untuk memurnikan montmorillonite (MMT) yang ada pada bentonit. Hasil MMT kemudian diseragamkan kation penyeimbangnya dengan Na+ menjadi Na-MMT. Selanjutnya menggunakan [Cu(en)2]2+, dihitung nilai Kapasitas Tukar Kation (KTK). Preparasi organoclay menggunakan Na-MMT dengan Monosodium Glutamat (MSG) sebagai agen penginterkalasi dan konsentrasi MSG yang ditambahkan sesuai dengan nilai 1 KTK dan 2 KTK. Hasil karakterisasi organoclay menunjukkan MSG telah berhasil terinterkalasi ke dalam MMT. Produk organoclay tersebut selanjutnya diuji kemampuan adsorpsinya terhadap kadmium dan timbal dengan variasi waktu, variasi konsentrasi dan variasi pH. Kemudian membandingkannya dengan kemampuan adsorpsi dari bentonit alam dengan konsentrasi kadmium dan timbal yang sama. Dari data yang diperoleh menunjukkan bahwa organoclay lebih efektif dari bentonit alam dalam menyerap kadmium dan timbal.

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Jambi Organoclay is a modified organoclay montmorillonite (MMT) with intercalation of organic cations in order to be organofilik. Before being used for the preparation, the first is the fractionation process to Jambi bentonite for purifying montmorillonite (MMT) which is in bentonite. Results MMT then homogenized with Na+ cations counterbalancing into Na-MMT. Furthermore, using [Cu(en)2]2+, calculated value Cation Exchange Capacity (CEC). Preparation of organoclay using Na-MMT with Monosodium Glutamate (MSG) as intercalate agent and concentration of MSG is added in accordance with the values 1 CEC and 2 CEC.

Organoclay characterization results indicate MSG has successfully intercalated into MMT. Organoclay products were then tested for their adsorption on cadmium and lead with time variation, concentration variation and pH variation. Then compare it with the adsorption capacity of natural bentonite with the same concentrations of cadmium and lead. From the data obtained show that the organoclay is more effective than the natural bentonite to absorb cadmium and lead."

"Penelitian yang bertujuan untuk mengetahui pengaruh logam berat timbal (Pb) terhadap perkecambahan biji kangkung (Ipomoea aquatica Forsk.) telah dilakukan. Konsentrasi timbal (Pb) yang digunakan yaitu 0, 50, 100, 150, dan 200 μM. Beberapa parameter telah diamati pada uji perkecambahan. Uji perkecambahan dilakukan dengan mengecambahkan masing-masing lima belas biji kangkung dengan enam ulangan dengan media perkecambahan berupa rockwool. Data yang diperoleh kemudian dianalisis menggunakan one-way ANOVA. Hasil uji perkecambahan menunjukkan terjadinya penurunan nilai seiring bertambahnya konsentrasi timbal (Pb) terhadap parameter berat basah tajuk dan akar, panjang tajuk dan akar, indeks vigor bibit/seedling vigor index (SVI), dan indeks toleransi (TI).

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The research study aimed to determine the effect of heavy metal lead (Pb) on the germination of water spinach (Ipomoea aquatica Forsk.). Lead (Pb) concentrations of 0, 50, 100, 150, and 200 μM were used. Several parameters were observed during the germination test, which involved germinating fifteen water spinach seeds per rockwool support with six replicates. The obtained data were analyzed using one-way ANOVA. The results of the germination test showed a decrease in shoot and root fresh weight, shoot and root length, seed vigor index (SVI), and tolerance index (TI ) as the lead (Pb) concentration increased."

"Kerang hijau bersifat sebagai filter feeder dalam perairan, sehingga komoditi ini sangat rentan terhadap akumulasi logam berat dalam tubuhnya. Diperlukan suatu usaha untuk meminimalkan kandungan logam berat pada kerang hijau, salah satu yang dapat dilakukan adalah proses depurasi. Pada penelitian ini, proses depurasi dilakukan denga metode kontinu, diskontinu dan ekstraksi asam. Waktu optimum depurasi metode kontinu adalah 1,5 jam, dengan kecepatan sirkulasi 250 L/jam dan didapatkan penurunan kadar logam Pb sebesar 30,048% dan 29,748% untuk logam Cu. Pada metode diskontinu, hasil optimum dicapai saat suhu 100°C dengan menggunakan media air PAM pada lama perendaman 3 jam dengan penurunan kadar logam Pb sebesar 35,001% dan kadar logam Cu 39,015%. Pada metode ekstraksi, kondisi optimum dicapai menggunakan pelarut asam asetat 11 % dengan penurunan logam Pb dan Cu masing-masing sebesar 88,243% dan 76,298%. Akibat proses depurasi ini, penurunan protein paling besar terjadi dengan perlakuan ekstraksi asam asetat 11%, dengan penurunan kadar protein sebesar 59,051% menggunakan metode Lowry dan 36,655 % menggunakan metode Kjeldahl.

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Green mussels are filter feeder in water hence, these commodities are susceptible to accumulate heavy metals in their body. Required an effort to minimize the content of heavy metals in green mussels, one that can be done by depuration process. In this study, the process conducted through continuous method, discontinuous method, and acid extraction methods. The optimum time of continuous method was 1.5 hours, with a circulation rate of 250 L/h and decreased levels of Pb obtained by 30,048% and 29,748% for Cu.

In the discontinuous method, the optimum result was achieved when using PAM aqueous media at 3 hours soaking time and 100°C of temperature. This method given decreased levels of Pb and Cu in 35,001% and 39.015%. In the extraction method, the optimum condition was achieved in a solvent extraction using 11 % acetic acid with decreased levels of Pb and Cu was 88,243% and 76,298%. For the determination of protein content, decreasing levels of the protein was obtained by treatment with 11% acetic acid extraction showed a decrease in protein content of 59,051% based on the Lowry method and 36,656% by the Kjeldahl method."