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"Perovskit LaFeO3 menunjukan sifat konduktivitas gabungan ionik dan elektronik yang dapat diaplikasikan sebagai solid oxide fuel cell. Untuk meningkatan efisiensi katoda solid oxide fuel cell digunakan berbagai macam cara salah satunya adalah merubah ukuran grain. Ukuran grain sangat penting untuk meningkatkan efisiensi dari katoda SOFC. Salah satu cara untuk merekayasa ukuran dari grain adalah menambahkan material komposit pada basis LaFeO3. Pada penelitian ini Fe3O4 ditambahkan pada LaFeO3 merupakan senyawa untuk menghambat pertumbuhan grain dari LaFeO3. Nanokomposit LaFeO3.0,1Fe3O4 dibentuk dari LaFeO3 yang disintesis dengan metode sol-gel. LaFeO3 dicampurkan dengan Fe3O4 dan disintering pada temperatur 1300°C selama 1 jam. Setelah proses sintering nanokomposit LaFeO3.0,1Fe3O4 di annealing dengan variasi temperatur 1000°C, 1100°C, 1200°C selama 12 jam. Struktur dan morfologi sampel dipelajari menggunakan metode karakterisasi XRD and SEM. Pola dari XRD menunjukan bahwa adanya double fasa LaFeO3 dan Fe3O4. Ukuran kristalit dari sampel berada di antara rentang 30-60 nm yang dihitung dari pola XRD menggunakan Schrerrer?s formula. Sifat listrik diukur sebagai fungsi frekuensi dan temperatur menggunakan metode spektroskopi impedansi pada frekuensi (1kHz ? 1MHz) dan temperatur (RT - 373 K). Sifat listrik direpresentasikan dengan plot Nyquist, plot Bode dan konstanta dielektrik (ɛ?) sebagai fungsi frekuensi. Fenomena relaksasi dielektrik pada plot Bode Zim vs f menunjukan pergeseran puncak ke frekuensi yang lebih besar. Dari kurva log f sebagai fungsi temperatur, nilai energi aktivasi terlihat memiliki ketergantungan terhadap ukuran grain.

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Perovskite LaFeO3 show the mixed electronic and ionic conductivity has enabled their use in applications such as solid oxide fuel cell cathodes . For increasing the eficiency of SOFC used some method as change the grain size. Grain size is very important to improve the efficiency of the SOFC cathode. One way to manipulate the size of the grain is to provide a composite material based to the LaFeO3. In this research, Fe3O4 is used as the compound to inhibit grain growth of LaFeO3. LaFeO3.0,1Fe3O4 nanocompsite made of LaFeO3 synthesized by the method solgel and mixed with Fe3O4 then sintered at 1300°C for 1h. LaFeO3.0,1Fe3O4 nano-composite was annealed at temperature of 1000°C, 1100°C, 1200°C for 12 h. Structural studies was carried out using X-ray diffraction (XRD) and SEM.

XRD pattern confirmed the double phase LaFeO3 and Fe3O4. The crystallite size of the synthesized material lie in the range 30-60 nm as calculated from X-ray diffraction pattern using Schrerrer?s formula. Electrical properties evaluated as a function of frequency, temperature using an impedance spectroscopy in frequency range (1kHz - 1MHz) and temperature ( RT-373 K) . Electrical properties represented in Nyquist plot, bode plot and dielectrict constant (ɛ?) as a fuction of frequency. The phenomena can be explained on the basis of Maxwell-Wagner type of interfacial polarization and hopping mechanism. The dielectric relaxation in the bode plot Z?? vs f shown the relaxation peak shift to the higher frequency. From vs log f as a function of a temperature, the activation energy was calculated and its value depend on the grain size."

"Telah diketahui bahwa deformasi plastis pada temperatur tinggi dapat meningkatkan sifat mekanis dari logam. Peningkatan sifat mekanis ini disebabkan oleh pengendalian struktur mikro. Sifat mekanis yang dihasilkan dipengaruhi oleh ukuran butir ferrit yang terbentuk. Pada penelitian kali ini dilakukan proses termomekanik terhadap baja HSLA A572 untuk mengetahui pengaruh besar reduksi pada temperatur tinggi terhadap distribusi ukuran butir ferrit.Didapatkan bahwa ukuran butir ferrit pada bagian ketebalan memiliki nilai yang berbeda. Perbedaan ukuran antara permukaan atas dan bawah tidak memiliki nilai yang sangat signifikan terhadap nilai kekerasan. Sementara itu ukuran butir bagian tengah pada dimensi ketebalan sampel memiliki nilai yang paling rendah untuk setiap variasi besar reduksi.

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It has been known that plastic deformation at high temperatures could increase the mechanical properties of a metal. Improved mechanical properties is due to the microstructure control. The resulting mechanical properties is influenced by the ferrite grain size. In the present study thermomechanical process was performed on A572 HSLA steels to investigate the influence of hot roll reduction at elevated temperature to the ferrite grain size distribution.

It was found that the ferrite grain size on the thickness has a different value for each position. Difference in size between the upper and lower surfaces have no significant value to the value of hardness properties. While the grain size at the center of the sample thickness dimension has the lowest value for any of the variation reduction."

"Data XRD dari nanokomposit Ti-Si-N telah dianalisis menggunakan program GSAS berbasis metode Rietveld untuk mengidentifikasa fasa-fasa pembentuk serta komposisinya dan mencari pengaruhnya terhadap kekerasan material tersebut. Telah ditemukan fasa-fasa baru dalam sampel tersebut, disamping fasa-fasa nanokomposit nc-TiN/a-Si3N4 & a-/nc-TiSi2 yang telah banyak dikenal. Dari fasa-fasa kristal yang diperoleh, setelah dilakukan perhitungan fraksi fasa amorf Si3N4 dan TiSi2 maka diperoleh bahwa kekerasan optimal terjadi pada kandungan a-Si3N4 8 wt.%.

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Phase composition analysis using rietveld methode and it?s influence to the hardness of Ti-Si-N nanocomposites. XRD data of nanocomposites Ti-Si-N have been analysed using GSAS based on Rietveld Method in order to identify phases and their composition as well as its influence on the hardness of these nanocomposites. Several new phases have been found in the sample beside the nc-TiN/a-Si3N4& a-/nc-TiSi2 that have been known widely. From the obtained crystalline phase, after the calculation of amorf Si3N4 and TiSi2 phase fraction, it is found that the optimum hardness can be reached when the fraction of a-Si3N4 phase around 8 wt.%."

"Industri pelat kuningan di Indonesia saat ini hanya menghasilkan pelat-pelat yang nilai tambahnya rendah, karena belum dikuasainya teknologi termomekanikal sebagai dasar rekayasa proses untuk pengembangan produk pelat, yang pada prinsipnya adalah rekayasa butir di dalam struktur mikro. Dalam penelitian disini akan dipelajari hubungan pengaruh kadar aluminium dibawah dan diatas 0,03% terhadap parameter proses anil cepat yaitu temperatur dan waktu tahan, terhadap Difraksi Sinar X, besar butir, struktur mikro, kekerasan, kekasaran dan mampu bentuknya, kemudian analisa dari hubungan tersebut, digunakan untuk mendapatkan kombinasi temperatur dan waktu tahan proses anil cepat, yang menghasilkan kemampuan bentuk optimal. Variabel dalam proses penelitian ini yaitu komposisi kadar aluminium memenuhi syarat (Al ≤ 0,03%) dan melebihi syarat (Al > 0,03%), pengaruh temperatur anil cepat yaitu 500°, 600° dan 700°C waktu tetap 3 menit, dan pengaruh waktu anil cepat yaitu 2,3 dan 4 menit temperatur tetap 600°C. Dari penelitian didapatkan kadar aluminium 0,16112% > 0,03% masih tergolong dalam kuningan 70/30 karena fasanya masih alfa, kemudian dengan semakin tingginya temperatur dan lamanya waktu anil cepat setelah pelat mengalami pengerolan dingin dengan reduksi 38%, terjadi penurunan besar butir rata-ratanya mengecil yaitu 11,742%, sedangkan penurunan kekerasan rata-ratanya membesar yaitu 51,05% berarti terjadi pertumbuhan butir, sehingga didapatkan temperatur dan waktu anil cepat optimal yaitu 600°C waktu 3 menit, kemudian diaplikasikan di pelat untuk menguji kemampuan bentuk melalui sampel uji tarik, ternyata elongasi, kekuatan tarik maksimal, koefisien pengerasan regang (n) dan anisotropi normal (r) mendekati referensi standar dan industri pengguna, untuk anisotropi planar (Δr) atau pengupingan sedikit diatas nilai nol. Kekasaran permukaan menurun dari pengerolan dingin ke proses anil cepat, akan tetapi distribusi kekasarannya masih tidak homogen. Dari pengerolan dingin melalui difraksi Sinar X didapat bidang (220) dan (111), setelah dianil terjadi penambahan satu bidang lagi yaitu (200).

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Currently brass sheet industry in Indonesia only produce low value added sheet product, because not yet understand the thermomechanical technology as the basic of process engineering for sheet product development. The basic process that is grain engineering in the sheet microstructure. In this research we will be studied the relation of aluminium content under and up specification 0,03%, to rapid annealing process parameter that is temperature and holding time, correlation to X Ray Diffraction, grain size, microstructure, hardness, and surface roughness, and then from this analysis relationship, applied to get combination of optimal temperature and rapid annealing process holding time, for getting the optimal sheet formability. Process parameter using in this research that is aluminium content below or over 0,03%, effect of anneal temperature such as 500°,600° and 700°C with fixed 3 minute holding time, and effect of anneal holding time such as 2,3 and 4 minute with fixed temperature of 600°C. Resulting from this research is got aluminium content that is 0,16112% > 0,03% still classify as brass 70/30 because only one phase in the microstructure that is alpha, then with increasing anneal temperature and holding time after the sheet experiences cold rolling with reduction 38%, exist mean grain size decreasing 11,742%, whereas mean hardness decreasing extend to 51,05%, these means happen enlarge of grain size, until got temperature and rapid anneal optimal that is 600°C with time 3 minute, then after apply to brass 70/30 sheet for testing sheet formability by tensile testing method. The results such as elongation, ultimate tensile strength, strain hardening coefficient (n), normal anisotropy (r) close to standard reference and user industry specification, for planar anisotropy (Δr) or earing tendency is little about zero. Although surface roughness declines from cold rolling to rapid annealing process, however distribution of its roughness still not homogen. From cold rolling resulting two plane such as (220) and (111), after that from rapid annealing process add one more plane that is (200) because crystal plane move to stabil condition after got cold rolling and rapis annealing."

"Variabel-variabel proses canai panas dapat ditentukan sedemikian rupa untuk memproduksi baja paduan dengan ukuran butir ferritdan sifat mekanis yang spesifik. Penelitian ini bertujuan untuk mengembangkan model ukuran butir ferrit akhir baja HSLA 0,028% Nb berdasarkan variabel-variabel operasional canai panas serta model kekerasan Vickers berdasarkan ukuran butir ferrit akhir.Hasilnya adalah bahwa ukuran butir ferrit akhir dapat diprediksi dari ukuran butir austenit semula, regangan, laju regangan, temperatur canai, dan laju pendinginan. Didapatkan juga bahwa kekerasan Vickers dapat diprediksi dari ukuran butir ferrit akhir, regangan, laju regangan, dan temperatur canai.

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Hot rolling variables can be determined as such to produce alloy steels having specific ferrite grain size and mechanical properties. The aim of this research is to develop model of ferrite grain size of 0,028%-Nb HSLA steel based on hot rolling operational variables and model of Vickers hardness based on the final ferrite grain size.

Results show that ferrite grain size can be predicted based on the initial austenite grain size, strain, strain rate, rolling temperature, and cooling rate. It is also found that Vickers hardness can be predicted based on the final ferrite grain size, strain, strain rate, and rolling temperature."

"Variabel-variabel proses canai panas dapat ditentukan sedemikian rupa untuk memproduksi baja paduan dengan ukuran butir ferritdan sifat mekanis yang spesifik. Penelitian ini bertujuan untuk mengembangkan model ukuran butir ferrit akhir baja HSLA 0,028% Nb berdasarkan variabel-variabel operasional canai panas serta model kekerasan Vickers berdasarkan ukuran butir ferrit akhir. Hasilnya adalah bahwa ukuran butir ferrit akhir dapat diprediksi dari ukuran butir austenit semula, regangan, laju regangan, temperatur canai, dan laju pendinginan. Didapatkan juga bahwa kekerasan Vickers dapat diprediksi dari ukuran butir ferrit akhir, regangan, laju regangan, dan temperatur canai.

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Hot rolling variables can be determined as such to produce alloy steels having specific ferrite grain size and mechanical properties. The aim of this research is to develop model of ferrite grain size of 0,028%-Nb HSLA steel based on hot rolling operational variables and model of Vickers hardness based on the final ferrite grain size. Results show that ferrite grain size can be predicted based on the initial austenite grain size, strain, strain rate, rolling temperature, and cooling rate. It is also found that Vickers hardness can be predicted based on the final ferrite grain size, strain, strain rate, and rolling temperature."

"A sedimentology survey was conducted during “Pelayaran Kebangsaan� research activities with a marine vessel of "Baruna Jaya VIII" in Karimun Java Sea. The objectives of the research were to determine the characteristics of marine water and its sediment, which are important control for coral reef growth in the study area. The survey acquired samples of Total Suspended Sediment (TSS) and gravity coring. Several analyses were then carried out on those samples; TSS analysis to determine the amount of suspended sediments in sea water that reflect the water quality for marine ecology, stratigraphic profile and sediment thickness pattern analyses to determine the sources of sediment, and grain-size analysis based on granulometry to determine deposition energy and grain-size distribution in the area. Those analyses were both conducted on-board Baruna Jaya VIII research vessel and P2O LIPI laboratory in Jakarta. The results showed that in Java Sea nearby Karimun Java Islands, the sediment supply came from the surrounding islands. Two sedimentary units were found in this area. The first units has thickness of tens centimeter from sea bed surface. It is characterized by grayish green color, grain size variation from clay to coarse sand, soft or low density and abundance with shells. The second unit is located beneath the first one, indicated by sharp contact. It is characterized by brownish color, higher density resembling the density of rock, less compacted and can be broken easily by hand, with occasionally thin carbon lenses or remnant of decomposed vegetation, and less shell or fossil At sea surface, TSS distribution shows value between 0.018 and 0.034 gr/l, with average of 0.025 gr/l, whereas at near bottom sea, it ranges between 0.024 and 0.030 gr/l, with average value of 0.027 gr/l. The granulometry shows that more than 50% of sediment is characterized by the abundance of grain size greater than 3 phi. It suggest that sea water around Karimun Java Islands was clear and the current was relatively calm. These conditions were relatively stable for a long time span. Those sea characteristics were important for successful growth of coral reefs and its complementary marine biotas. However, further studies and researches based on chemical and physical characteristics of sea water, and plankton and microbiology variation and abundances are necessary to confirm those presuppositions"

"ABSTRAKPenelitian terhadap proses penghalusan butir harus dilakukan pada saat ini untuk mendapatkan material dengan sifat mekanis yang baik yang diharapkan dapat bermanfaat untuk masa depan industri. Penelitian ini bertujuan untuk mengetahui pengaruh variasi temperatur canai hangat multi pass dan waktu tahan terhadap kekerasan, struktur mikro, dan besar butir baja karbon rendah. Sampel dideformasi pada temperatur 500˚C dan 550˚dengan waktu tahan dan 10 menit dan derajat deformasi 20%-20%-20%-20%. Kemudian di-quench dengan media air. Hasil penelitian menunjukkan bahwa semakin rendah temperatur canai hangat maka butir yang dihasilkan semakin halus dan kekuatan material yang dihasilkan juga lebih tinggi. Selain itu semakin singkat waktu tahan maka butir yang dihasilkan semakin halus dan kekuatan material yang dihasilkan juga lebih tinggi. Hasil yang didapatkan dari temperatur canai yang lebih rendah dan waktu tahan lebih singkat adalah ukuran butir 17,19 2m dengan nilai kekuatan 621 MPa.

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ABSTRACTNowadays, the research of grain refinement process must be done, to get material with good mechanical properties that expected will be benefit for industry in the future. The object of the present work is to investigate the effect of temperature and delay time warm rolling multi pass on hardness, microstructure, and grain size of Low Carbon Steel. The samples deformed at temperature of 500 and 550 with holding time of and 10 minutes and the degree of deformation of 20% -20% -20% -20%. Then, the samples were quenched by water. Experimental results have shown that the lower the temperature of warm roll produced finer grain and higher strength. Shorter holding time produce finer grain and higher strength. The results obtained from the rolled lower temperatures and shorter holding time is the grain size of 17.19 2m with 621 MPa. "