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"Gemuk bio overbased kalsium sulfonat kompleks dibuat dari minyak kelapa sawit terepoksidasi yang digunakan sebagai base oil dan overbased kalsium sulfonat kompleks sebagai thickening agent. Thickening agent yang digunakan dalam penelitian ini adalah kalsium sulfonat, kalsium karbonat, dan kalsium hidroksida sebagai sabun utama (overbased kalsium sulfonat) serta kalsium oleat terepoksidasi dan kalsium asetat (kalsium oleat-asetat) sebagai pengompleksnya. Perbandingan campuran kalsium sulfonat-karbonat-hidroksida sebagai overbased kalsium sulfonat dengan kalsium oleat terepoksidasi-asetat sebagai pengompleks yaitu 5% : 95% dan 50% : 50%. Gemuk ini dihasilkan dari proses saponifikasi yang menggunakan reactor batch tertutup, dilanjutkan dengan proses pendinginan, dan terakhir proses homogenisasi. Pengaruh variasi komposisi pengompleks sebagai thickener dapat dilihat dari pengujian karakteristik gemuk bio yang terdiri dari uji sifat fisik dan kimia seperti uji tampilan gemuk, uji mulur, uji penetrasi, dan uji dropping point, serta uji four ball untuk mengetahui performa dari gemuk. Hasil terbaik yang didapat pada perbandingan overbased kalsium sulfonat : kalsium oleat-asetat sebesar 5% : 95% yaitu gemuk dengan komposisi thickening agent 35% dengan rentang penarikan mulur 9.5 cm, tingkat konsistensi NLGI #2, nilai dropping point 250˚C, dan nilai keausan sebesar 0.2 mg. Untuk gemuk dengan perbandingan overbased kalsium sulfonat : kalsium oleat-asetat sebesar 50% : 50% yaitu gemuk dengan komposisi thickening agent 50% dengan rentang penarikan mulur 7 cm, tingkat konsistensi NLGI #2, nilai dropping point 269˚C, dan nilai keausan sebesar 0.3 mg.

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Overbased calcium sulfonate grease bio complex is made from palm oil epoxidized as a base oil and overbased calcium sulfonate complex as a thickening agent. Thickening agent used in this study is calcium sulfonate, calcium carbonate, and calcium hydroxide as a major soap (overbased calcium sulfonate) and epoxidized oleic calcium and acetate calcium (oleic-acetate calcium) as complexing. Comparison of a mixture of calcium sulfonate-carbonate-hydroxide as overbased calcium sulfonate with epoxidized oleic calcium-acetate calcium as complexing is 5% : 95% and 50% : 50%.

This grease is produced from the saponification process which uses a closed batch reactor, followed by a cooling process, and the final homogenization process. Effect of complexing composition variations as a thickener can be seen from the test characteristics of bio grease, consisting of physical and chemical properties test such as a test to see grease, creep testing, penetration testing, dropping point testing, and four ball test to determine the performance of the grease.

The best results were obtained in comparison overbased calcium sulfonate : oleic calcium-acetate at 5% : 95% are grease with thickening agent composition of 35% with a range of 9.5 cm, the level of consistency of NLGI # 2, the value of dropping point 250˚C, and value of wear 0.2 mg. For the grease by comparison overbased calcium sulfonate : oleic calcium-acetate at 50% : 50% are grease with thickening agent composition of 50% with a range of 7 cm, the level of consistency of NLGI # 2, the value of dropping point 269˚C, and anti-wear value is 0.3 mg."

"ABSTRAKPada pembuatan gemuk bio ini digunakan Kalsium karbonat atau CaCO3 berukuran submikro-mikro sebagai aditif padat untuk meningkatkan sifat antiwear dari gemuk bio yang dihasilkan dengan NLGI #2. Penelitian ini diawali dengan pengepoksidasian minyak sawit pada suhu 65 ˚C; sintesis gemuk bio yang meliputi proses pengadukan, pemanasan, dan saponifikasi pada suhu maksimum 165 ˚C; homogenisasi pada suhu 70 ˚C; serta pengujian karakteristik dan performa gemuk bio yang meliputi uji konsistensi, uji dropping point, serta four ball test untuk menguji sifat antiwear gemuk bio dengan kecepatan putaran sebesar 1150 rpm. Adapun variabel yang terdapat pada penelitian ini yaitu waktu dan suhu selama proses sebagai variabel control; komposisi aditif CaCO3 sebagai variabel bebas; ukuran partikel CaCO3, komposisi base oil, thickener agent, dan BHT serta hasil uji karakteristik sebagai variabel terikat. Hasil yang didapat yaitu gemuk bio NLGI #2 dengan dropping point pada suhu 301 ˚- 317 ˚C. Untuk hasil pengujian antiwear terbaik didapat pada gemuk bio dengan penambahan 3,5% CaCO3 submikro-mikro dengan pengurangan massa ball bearing sebesar 0,7 mg, sementara pada gemuk bio dengan 0% CaCO3 pengurangan tersebut sebesar 250 mg.

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ABSTRACTIn the making of this bio grease, calcium carbonate or CaCO3 in submicro-micro size is used as a solid additive to increase its antiwear properties. To start the research, the epoxidation of palm oil in 65 ˚C is done first; and then synthesizing of bio grease which consists of mixing, heating, and saponification with maximum temperature at 165 ˚C; homogenization in 70 ˚C; and characterization tests that includes the concistency test, dropping point test, and four ball test. The variable contained in this research are time and temperature as control variable; composition of CaCO3 as independent variable; CaCO3 particle size, composition of base oil, thickener agent, BHT, and the result of characterization test as dependent variable. To start the research, the epoxidation of palm oil is done first, and then synthesizing of bio grease, and characterization testing that includes the elasticity test, concistency test, dropping point test, and four ball test in 1150 rpm. The results of this research are, the bio grease has NLGI #2 with 301 ˚- 317 ˚C in dropping point test. For the antiwear test, the best result is possessed by bio grease with 3.5% of CaCO3 addition with reduction of mass ball bearing as much as 0.7 mg, meanwhile in bio grease with 0% of CaCO3 gave 250 mg reduction of mass ball bearing."

"Kalsium karbonat merupakan aditif padat yang dapat meningkatkan performa anti-wear pada pelumas gemuk. Kinerja aditif dalam mengurangi jumlah keausan dipengaruhi oleh ukuran partikelnya, dimana ukuran partikel yang semakin kecil akan memberikan sifat ketahanan aus yang semakin baik. Namun, partikel yang semakin kecil akan memiliki harga yang semakin mahal. Penelitian ini bertujuan untuk meningkatkan performa gemuk dalam mengurangi jumlah keausan dan memaksimalkan efisiensi biaya dengan mengkombinasikan ukuran partikel aditif kalsium karbonat, yaitu ukuran mikro diatas asperities (Mb), ukuran mikro dibawah asperities (Mk) dan ukuran nano (N). Tiga ukuran tersebut dikombinasikan dengan komposisi berbeda. Pembuatan gemuk dilakukan melalui reaksi saponifikasi minyak sawit sebagai bahan dasar dengan asam 12-hidroksistearat, kalsium hidroksida, dan asam asetat sebagai pengental dan pengompleks. Gemuk bio kalsium kompleks dengan tingkat kekerasan gemuk multiguna (NLGI 2) yang dihasilkan selanjutnya dicampur dengan bubuk aditif kalsium karbonat sebanyak 1% dari basis gemuk, Partikel dikarakterisasi ukurannya menggunakan SEM. Gemuk yang dihasilkan dilakukan pengujian untuk mengetahui jumlah keausan menggunakan uji four ball dan untuk mengetahui pengaruh terhadap karakteristik gemuk yaitu konsistensi, kemuluran, dan dropping point. Hasil penelitian menunjukkan bahwa pada kombinasi mikropartikel dibawah ukuran asperities dan nanopartikel dengan rasio 50% : 50% menghasilkan performa terbaik dalam mengurangi keausan dan mengurangi biaya bahan baku pembuatan gemuk. Penambahan aditif tidak terlalu memengaruhi tingkat penetrasi, kemuluran dan dropping point.

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Calcium carbonate is a solid additive that is well-known for improving the anti-wear performance of bio greases. The performance of additives in reducing the amount of wear can be affected by its particle size, where the smaller particle size will provide better anti-wear performance. However, smaller particles are more expensive. Therefore, research is needed on the particle size combination of calcium carbonate particles on tribological performance to reduce the amount of wear and achieve cost efficient grease. The grease is made through the saponification reaction of palm oil as base oil with 12-hydroxystearic acid, calcium hydroxide, and acetic acid as thickeners and complexing agents. The resulting NLGI 2 calcium complex bio-grease (multi-purpose grease) was then mixed with 1% w/w calcium carbonate powder. The additive particle size was varied into three sizes: micro size above asperities (Mb), micro size below asperities (Mk), and nano size (N). The sizes were varied by its compositions. Particles were characterized using SEM, meanwhile bio-grease using penetration, drop point, and four ball tests. The results showed that the combination of microparticles below asperities (Mk) and nanoparticles (N) with a ratio of 50% : 50% produced the best performance in reducing wear and reducing the cost of raw material for making grease. The addition of additives does not significantly affect the level of penetration, fibril texture and dropping point."

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Partikel padat grafit telah diketahui digunakan sebagai aditif anti-wear untuk meningkatkan performa gemuk. Skala ukuran partikel padat, khususnya nanopartikel memiliki peran utama dalam mengurangi jumlah keausan secara signifikan. Namun, harga nanopartikel jauh lebih mahal dibandingkan mikropartikel. Penelitian ini bertujuan untuk meningkatkan performa gemuk bio kalsium kompleks dalam mengurangi jumlah keausan dengan mengkombinasikan nanopartikel dan mikropartikel dengan ukuran berturut-turut yaitu 41 nm hingga 71 nm dan 1 𝜇𝑚 hingga 3,9 𝜇𝑚. Komposisi nanopartikel : mikropartikel divariasikan dalam kombinasi dengan interval 10% dalam 1% dari total basis gemuk. Penelitian diawali dengan pembuatan gemuk menggunakan minyak RBDPO (Refined, Bleached, Deodorized Palm Oil) sebagai minyak dasar serta asam 12-Hidroksi stearat dan asam asetat sebagai pengental. Partikel grafit didispersikan pada saat homogenisasi gemuk. Hasil penelitian menunjukkan bahwa pada kombinasi perbandingan nanopartikel dan mikropartikel dengan rasio 40% : 60% menunjukkan adanya efek kinerja kombinasi antara nanopartikel dan mikropartikel dalam mengurangi jumlah keausan, dimana pada komposisi rasio 50% : 50% dan 60% : 40% menghasilkan performa terbaik dalam mengurangi keausan dibandingkan hanya menggunakan nanopartikel saja, dengan demikian ukuran kombinasi nano-mikro juga dapat mengurangi biaya bahan baku pembuatan gemuk dengan 100% nanopartikel. Selain itu, seiring dengan peningkatan komposisi nanopartikel dalam kombinasi maka konsistensi dan nilai dropping point gemuk.

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Solid particles of graphite have been known to be used as an anti-wear additive to improve grease performance in reducing wear. The size scale of solid particles, especially nanoparticles has a major role in reducing the amount of wear significantly. However, the price of nanoparticles is much more expensive than microparticles. This study aims to improve the performance of bio calcium complex grease in reducing wear by combining nanoparticles and microparticles with sizes 41 to 71nm and 1 to 3.9 . The composition of nanoparticles: microparticles were varied in combination with an interval of 10% within 1% of the total grease base. The synthesis of grease using RBDPO oil as a base oil and 12-Hydroxystearic acid and acetic acid as thickeners. The graphite particles are dispersed during the homogenization of the grease. The results showed that the combination of the ratio of nanoparticles and microparticles with a ratio of 40%: 60% showed a performance effect of the combination of nanoparticles and microparticles in reducing the amount of wear, where the composition ratios of 50%: 50% and 60%: 40% produced the best performance in reducing wear compared to using only nanoparticles, thus nano-micro combination can also reduce the cost of grease material by 100% nanoparticles. In addition, along with the increase in the composition of the nanoparticles in the combination, the consistency and dropping point value of the grease increases.

 

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"ABSTRAKLatar belakang : Penggunaan konsentrasi kalsium dialisat ([Ca-D]) masih kontroversi. Di Indonesia masih digunakan [Ca-D] yang berbeda-beda antara 1,25 mmol/L ? 1,85 mmol/L. Studi DOPPS mendapatkan kegagalan dalam pencapaian kadar kalsium (Ca), fosfat (PO4), produk CaxP dan hormon paratiroid (HPT) sesuai yang ditargetkan K/DOQI dan semua penyebab risiko mortalitas secara signifikan berhubungan dengan tingginya [Ca]-D

Tujuan : Mengetahui perbedaan kadar Ca darah, PO4, HPT dan kalsifikasi vaskular pada penggunaan [Ca]-D tinggi dan rendah. Metode : Penelitian adalah studi potong lintang analitik dilakukan di Unit Hemodialisis Divisi Ginjal-Hipertensi RS Cipto Mangunkusumo, Jumlah subyek 46 orang. Dua puluh tiga pasien menggunakan [Ca]-D rendah (1,25 mmol/L) dan 23 pasien menggunakan [Ca]-D tinggi (1,85 mmol/L). Penelitian dilakukan Oktober 2013 ? Mei 2014. Analisis statistik dengan uji Mann Whitney dan uji Chi square. Menggunakan SPSS 20.0.Hasil : Sebanyak 46 pasien, terdiri dari 25 laki-laki dan 21 perempuan, dengan rerata usia 50,87 + 12,74 tahun. Lama HD 45,50 (6-168 bulan). Subyek penelitian yang mencapai target kontrol metabolisme sesuai panduan K/DOQI 2002 pada [Ca]-D rendah : Ca terkoreksi, PO4, produk Ca xPO4, dan HPT yang mencapai target sebanyak 8(34,8%), 10(43,5%), 15(65,2%) dan 2(8,7%) pasien. Pada [Ca]-D tinggi didapatkan 10(43,5%), 8(34,8%), 15(65,2%), 8(34,8%) pasien. Penelitian kami mendapatkan dengan [Ca]-D tinggi hasil lebih baik, hal ini tidak sama dengan hasil penelitian DOPPS. Berbeda dengan PO4 yang hasilnya lebih baik dengan [Ca]-D rendah, namun hasil kami juga lebih baik dari penelitian DOPPS. Hasil pada HPT lebih buruk pada [Ca]-D rendah dibandingkan DOPPS, hal ini mungkin disebabkan kami tidak menggunakan vitamin D untuk mengatasi hiperparatiroid sekundernya. Kalsifikasi vaskular dengan metode KAA pada [Ca]-D tinggi sebanyak 13(48,1%) sedangakan pada [Ca]-D rendah sebanyak 14(51,9%). Dengan metode KAAb pada [Ca]-D tinggi didapatkan kalsifikasi sebanyak 16(47,1%) dan pada [Ca]-D rendah didapatkan 18(52,9%) kalsifikasi. Simpulan : Terdapat perbedaan kadar Ca, PO4, produk Ca x PO4, HPT dan kalsifikasi vaskular, pada penggunaan [Ca]-D tinggi dan rendah, tetapi yang berbeda bermakna hanya Ca dan HPT.

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ABSTRACTBackground : The use of calcium dialysate is still controversial. In Indonesia, the dose for [Ca-D] still varies between 1,25 mmol/L ? 1,85 mmol/L. DOPPS study shows failure in achieving optimal calcium, phosphate as well as parathyroid hormone level in the blood as targetted by K/DOQI and is related to significantly increased mortality and is closely related with increased [Ca]-D.Aim : Evaluate the difference in Serum Ca, PO4, PTH levels and vascular calcification in concentrations of [Ca]-D high and low.Methods : This is a cross sectional study done in Hemodialysis unit in Nephrology Division of Cipto Mangunkusumo hospital. Total subject recruited was 46 patients, 23 patient using low concentration [Ca]-D (1.25 mmol/L) and 23 patients using high concentration [Ca]-D (1.85mmol/L). Research was conducted in October 2013 until May 2014. Analysis was performed using Mann Whitney test and Chi Square, statistical analysis was done using SPSS 20.0.Result : A total of 46 patients consisting of 25 men and 21 women, with mean age of 50,87 + 12,74 years. Mean length of Dialysis was 45,50 months (6-168 months). Subjects using low concentration [Ca]-D who reached target concentration according to K/DOQI consisted of : corrected Ca in 8 (34,8%) patients while in high concentration [Ca]-D consisted of 10(43,5%) patients, better than DOPPS study. In terms of phosphate levels, low concentration [Ca]-D achieved target PO4 level in 10(43,5%) patients while high concentration [Ca]-D achieved target in 8(34,8%) patients. Corrected Ca x PO4 target levels were obtained equally in both groups which was 15(65,2%) patients. Target PTH level was achieved in low concentrated [Ca]-D up to 2(8,7%) patients, very low may be caused we did not use vitamin D and 8(34,8%) patients in high concentrated [Ca]-D. Vascular calcification using KAA method showed incidence of 13(48,1%) in high concentrated [Ca]-D and 14(51,9%) in low concentrated [Ca]-D group. On the other hand, KAAb methods revealed calcification of 16(47,1%) in high concentrated [Ca]-D and 18(52,9%) calcification in low concentrated [Ca]-D.Conclusion : There is a difference in Ca, PO4, Ca X PO4 product serum level and vascular calcification in high and low [Ca]-D in both group however, statistically significant difference was found only in serum Ca and PTH levels."

"Gemuk kalsium kompleks berpotensi digunakan dalam aplikasi food grade H-1. Agen pengompleks yang paling umum digunakan adalah asam asetat sedangkan asam azelat banyak digunakan sebagai agen pengompleks dalam gemuk litium kompleks, di mana kedua asam pengompleks rantai pendek ini memberikan gemuk dengan peforma yang sangat baik bila digunakan secara terpisah. Dalam penelitian ini, gemuk bio kalsium kompleks disintesis dengan menggunakan minyak goreng kelapa sawit sebagai minyak dasar, asam 12 – hidroksistearat sebagai asam lemak, bersama dengan kombinasi asam asetat dan asam azelat sebagai agen pengompleks. Gemuk dibuat dengan cara saponifikasi, diikuti dengan pendinginan dan homogenisasi. Komposisi campuran asam asetat dan asam azelat divariasikan untuk menunjukkan pengaruh interaksi antara kedua agen pengompleks ini yang ditentukan dengan melakukan uji peforma gemuk. Gemuk bio kalsium kompleks yang dihasilkan dari kombinasi ca-asetat dan ca-azelat memiliki NLGI 2 dengan sifat anti-aus dan mulur yang sangat baik dibandingkan hanya menggunakan satu agen pengompleks, dengan komposisi rasio persen berat terbaik dari asam asetat/asam azelat berada pada 80:20. Namun, dropping point yang dicapai masih lebih rendah dibanding ketika gemuk bio kalsium kompleks dibuat hanya dengan menggunakan asam asetat.

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Calcium complex grease has the potential to be used in H–1 food-grade application. The most common complexing agent used is acetic acid while azelaic acid is widely used as a complexing agent in lithium complex grease where these two short-chain complexing acids provide the final grease with great performance when used individually. In this study, calcium complex grease was synthesized by using palm oil as base oil, 12 – hydroxystearic acid as fatty acid, along with combination of acetic and azelaic acids as the complexing agents. Grease was manufactured by saponification, followed by cooling and homogenization. The weight percent composition of acetic acid and azelaic acid was varied to indicate the effect of the interaction between these two complexing agents which was determined by grease performance characteristic tests. The combination of ca-acetate and ca-azelaic as complexing salts in grease formulation had NLGI grade 2 consistency with excellent anti-wear properties and grease tackiness compared to calcium complex bio grease contains only single complexing agent, with the best weight percent ratio composition of acetic acid/azelaic acid was at 80:20. However, the dropping point achieved was still lower than when acetic acid was used alone in the formulation of calcium complex bio grease."

"Bone mineral content at old age is dependent upon the peak bone mass achieved in youth and subsequent adult bone loss (Matkovic, 1992). Adequate calcium consumption during childhood is beneficial for the acquisition of peak bone mass and density. It is therefore, calcium has been considered to play important role in the pathogenesis of osteoporosis (NIH, 1994), and osteoporosis has been described as a pediatric disease that manifests itself in old age (Lysen and Walker, 1997). If children fail to take in enough calcium, they are more likely to develop osteoporosis later in life (Insel et al., 2002). Nevertheless, calcium is one of the nutrients that most likely to be low or deficient in children's diets (Krause's, 2000). Recently, calcium has been suspected to have a positive effect in preventing some disorders, including diarrhea. Bovee et al., (2003) indicated that low calcium intake has been shown to impair host resistance to food-borne intestinal infections. Because of childhood morbidity and mortality due to infectious diarrhea is very high in developing countries, adequate dietary calcium intakes of the children will likely improve their bone as well as intestinal health (Bovee et al., 2003). Dairy products are always regarded as primary source of calcium. It is difficult to meet the RDA for calcium without milk or milk products (Krause, 1992). Unfortunately, the general Indonesian population does not commonly consume milk.

The results of 1997 national survey on households' food consumption pattern across provinces in Indonesia reveal that milk consumption was zero, or milk product was never consumed in the last three months at the time of survey (Sumarno at al., 1997). In line with the 1997 national survey, Ariani et al., (1997) reported that the level of milk consumption was lower than that of other animal products across the provinces in Indonesia, and in general, milk consumption of Indonesian population was below the standard of adequacy of milk consumption according to Widyakarya National Pangan dan Gizi 1998 (4.6 kg/cap/year). The above facts indicate that many Indonesians may consume calcium-deficient diet."

"Gemuk merupakan pelumas semi-solid yang secara luas diaplikasikan untuk mengurangi gesekan, panas, dan keausan pada permukaan mesin yang bergesekan. Gemuk overbased calcium sulfonate (Ca-sulfonat) memiliki performa antiwear sama baiknya dengan gemuk yang ditambahkan aditif anti-wear. Gemuk ini dibuat menggunakan minyak goreng kelapa sawit sebagai minyak dasar dengan Linear Alkyl Benzene Sulfonic Acid (LABSA), kalsium hidroksida, dan kalsium karbonat sebagai pengental. Pada penelitian ini dilihat pengaruh penambahan Ca-sulfonat terhadap gemuk kalsium oleat kompleks (Ca-oleat-asetat) untuk mengurangi keausan. Gemuk Ca-oleat-asetat terdiri dari asam oleat epoksidasi sebagai asam lemak serta asam asetat sebagai agen pengompleks. Gemuk Ca-oleat-asetat divariasikan dalam rentang 0 – 100% untuk mendapatkan gemuk NLGI 2 atau multipurpose grease. Gemuk dibuat dengan cara mencampurkan semua bahan di reaktor terbuka, sebutan gemuk gabungan ini adalah gemuk Ca-oleat-sulfonat. Gemuk mengalami proses saponifikasi, pendinginan, dan homogenisasi menggunakan hand mixer. Selanjutnya dilakukan uji karakteristik performa gemuk yaitu uji penetrasi, uji tekstur fibril, uji dropping point, dan uji four ball dengan kecepatan putaran 1150 rpm dan beban 62 kg selama 60 menit. Gemuk Ca-oleat-sulfonat yang dihasilkan memiliki performa anti-wear dan panjang mulur yang lebih baik dibandingkan gemuk 100% Ca-oleat-asetat. Persentase gemuk terbaik Ca-oleat-asetat/Ca-sulfonat berada pada 50:50 yang mengandung 38,2% sabun dari total massa gemuk dengan hasil nilai keausan 0,7 mg; kemuluran 4,6 cm; dan dropping point 220 °C.

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Grease is a semi-solid lubricant widely applied to reduce friction, heat, and wear on rubbing machine surfaces. Overbased Calcium Sulfonate Grease (Ca-sulfonate) has anti-wear performance comparable to grease with added anti-wear additives. This grease is made from palm cooking oil as a base oil with Linear Alkyl Benzene Sulfonic Acid (LABSA), calcium hydroxide, and calcium carbonate as a thickener. This study is to know how adding Ca-sulfonate affects calcium oleic complex grease (Ca-oleic-acetate) in reducing wear. Ca-oleic-acetic grease consists of epoxidized oleic acid as a fatty acid and acetic acid as a complexing agent. Ca-oleic-acetate grease is varied in the 0 – 100% range to get NLGI 2 grease or multipurpose grease, combination of grease is called Ca-oleic-sulfonate grease. Grease was manufactured by mixing all the ingredients in an open reactor. Grease went through saponification, cooling, and homogenization using a hand mixer. Furthermore, grease performance characteristics such as penetration, fibril texture, dropping point, and four balls at 1150 rpm and 62 kg for 60 minutes were tested. The best grease percentage of Ca-oleic-acetate/Ca-sulfonate was at 50:50, which contains soap 38.2% of the total mass of grease with 0.7 mg of wear, tackiness of 4.6 cm, and a dropping point of 220 °C."

"Pada penelitian ini dibuat gemuk bio ramah lingkungan overbased kalsium sulfonat kompleks yang memiliki sifat antiaus tinggi. Base oil yang digunakan adalah minyak sawit terepoksidasi sedangkan thickening agentnya adalah campuran kalsium sulfonat-karbonat-borat sebagai sabun utama dan kalsium oleat-asetat sebagai pengompleks. Gemuk ini melalui proses saponifikasi pelarutan-pendinginan-homogenasi. Komposisi sabun pengompleks ditetapkan pada 4,5%, 7%, 9,5% dan jumlah thickening agent total divariasikan untuk mendapatkan gemuk NLGI #2 (multipurpose). Gemuk terbaik yang dihasilkan memiliki suhu dropping point 211°C, yaitu pada komposisi thickening agent 52,5% dengan perbandingan sabun utama 90,5% dan sabun pengompleks 9,5%. Uji keausan dengan four ball test menggunakan steel ball specimen 8,1 mm pada 1150 rpm dan load 62 kg menghasilkan nilai koefisien friksi yang kecil yaitu 0,056.

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This research studies the synthesis of bio grease environmental friendly overbased calsium sulfonate complex which has high anti-waer properties. We used epoxidized palm oil as base oil, whereas thickening agent is a mixture of calsium sulfonate-carbonate-borate as primary soap and calsium oleic-acetat as a complex agent. The bio-grease was made through the process of saponification dissolution-cooling-homogenization. The composition of soap complexing agent composition was set at 4.5%, 7%, 9.5%, and the total number of thickening agent was varied to obtain grease of NLGI #2 (multipurpose). The best resulted grease has a dropping point temperature of 240°C, with the thickening agent composition of 52.5% while the ratio of primary soap 90.5% and soap complexing agent 9.5%. Wear test using four ball test using steel ball specimen 8.1 mm at 1150 rpm and 62 kg load, produces small coefficient friction value, which is 0.056."

"Gemuk bio overbased kalsium sulfonat kompleks dibuat menggunakan minyak" sawit terepoksidasi sebagai base oil dan overbased kalsium sulfonat kompleks sebagai thickening agent. Thickening agent pada penelitian ini teridiri dari kalsium sulfonat, kalsium karbonat dan kalsium hidroksida sebagai sabun utama serta kalsium oleat terepoksidasi dan kalsium asetat sebagai pengompleksnya. Gemuk ini dibuat dengan proses saponifikasi di reaktor batch tertutup, dilanjutkan dengan pendinginan dan homogenisasi. Pengaruh sabun kalsium sulfonat kompleks terhadap kualitas gemuk dapat terlihat pada uji karakteristik seperti penetrasi, dropping point dan four ball test untuk mengetahui performa gemuk. Gemuk paling baik dihasilkan pada komposisi thickening agent 50 % dengan variasi overbased detergent 90,5 % dan pengompleks 9,5 %. Gemuk ini memiliki tingkat konsistensi NLGI 2 dan nilai dropping point 279°C. pada four ball test gemuk bio overbased kalsium sulfonat menggunakan kalsium oleat dan kalsium asetat sebagai pengompleks menghasilkan nilai keausan kecil yaitu 0,09 mg.

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Overbased calcium sulfonate greases bio complex created using epoxidized palm oil as the base oil and overbased calcium sulfonate complex as a thickening agent. Thickening agent consist of calcium sulfonate, calcium carbonate and calcium hydroxide as the main soap and epoxidized oleic calcium and calcium acetate as a complexing. Grease is made by saponification process in a closed batch reactor, followed by cooling and homogenization. Effect of calcium sulfonate complex soap greases to quality can be seen in characteristics such as penetration testing, dropping point and four-ball test to determine performance greases. Best grease resulting in thickening agent composition of 50% with a variation of 90.5% overbased detergent and complexing 9.5%. It has the consistency of grease NLGI 2 and dropping point value of 279°C. On four ball test, overbased calcium sulfonate bio greases using oleic calcium and calcium acetate as a complexing produces small anti-wear value is 0.09 mg."