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"This study evaluated the volatile components of liquid smoke from coconut shells obtained through the pyrolysisprocess at fraction 350-420 C. The volatile compounds of liquid smoke from a coconut shell were analyzed using gaschromatography and mass spectrometry (GC-MS). Nineteen peaks were detected by GC-MS in the coconut shell liquidsmoke, and 19 compounds also were identified. The volatile compounds were identified as follows based on theirfunction group?s composition percentage: phenol (90.75%), carbonyl (3.71%), alcohol (1.81%), and benzene (3.73%),respectively. The liquid smoke contains a high ratio of phenol derivatives (90.75%) in volatile profile. The phenolderivatives were the major volatile compounds found in the coconut shell liquid smoke.Senyawa Volatil terdeteksi pada Asap Cair Tempurung Kelapa melalui Pirolisis pada Suhu Fraksinasi 350-420C. Penelitian ini mengevaluasi komponen volatil asap cair dari tempurung kelapa yang diperoleh melalui prosespirolisis pada fraksi 350-420 C. Senyawa-senyawa volatil asap cair dari tempurung kelapa dianalisis menggunakankromatografi gas dan spektrometri massa (GC-MS). Sembilan belas puncak terdeteksi oleh GC-MS dalam asap cairtempurung kelapa, dan 19 senyawa juga telah diidentifikasi. Senyawa-senyawa volatil diidentifikasi berdasarkan persenkomposisi dari gugus fungsi masing-masing sebagai berikut: fenol (90,75%), karbonil (3,71%), alkohol (1,81%), danbenzene (3,73%). Asap cair mengandung rasio tinggi turunan fenol (90,75%) yang mudah menguap. Derivatif fenoladalah senyawa volatil utama yang ditemukan dalam asap cair tempurung kelapa."

"Three flavonoid compounds, kaempferol (1), kaempferol-3-O-α-L-rhamnoside (2), and kaempferol-3-O-β-D-glucosyl-α-L-rhamnoside (3), were isolated from the bark of Aglaia eximia (Meliaceae). The chemical structures of compounds 1?3 were identified with spectroscopic data, including UV, IR, NMR (1H, 13C, DEPT 135°, HMQC, HMBC, 1H-1HCOSY NMR), and MS, as well as a compared with previously reported spectra data. All compounds were evaluated for their cytotoxic effects against P-388 murine leukemia cells. Compounds 1?3 showed cytotoxicity against P-388 murine leukemia cells with IC50 values of 1.22, 42.92, and >100 mg/mL, respectively.

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Senyawa Flavonoid dari Kulit Batang Aglaia eximia (Meliaceae). Tiga senyawa flavonoid, kaempferol (1), kaempferol-3-O-α-L-ramnosida (2), dan kaempferol-3-O-β-D-glukosil-α-L-ramnosida (3), diisolasi dari batang Aglaia eximia (Meliaceae). Struktur kimia senyawa 1?3 diidentifikasi berdasarkan data spektroskopi, meliputi UV, IR, NMR (1H, 13C, DEPT 135°, HMQC, HMBC, 1H-1H-COSY NMR), dan MS, serta perbandingan dengan data spektra yang diperoleh sebelumnya. Seluruh senyawa dievaluasi pengaruh sitotoksiknya terhadap sel murine leukimia P-388. Senyawa 1-3 menunjukkan aktivitas sitotoksik terhadap sel murine leukimia P-388 dengan nilai IC50 berturut-turut 1,22; 42,92, dan >100 mg/mL."

"Two flavonoid compounds, 5,7,3?,4?-tetrahydroxy-6-geranylflavonol (1) and kaempferol 7-O-β-glucose (2) have beenisolated from the leaves of Macaranga hispida (Blume), Mull.Arg. Isolation and purification were conducted bychromatography methods and chemical structure characterization was carried out by spectroscopic methods. The5,7,3?,4?-tetrahydrxyi-6-geranyl flavonol (1) and kaempferol 7-O-glucose (2) had moderate cytotoxic activity againstmurine leukemia P-388 cell lines with IC50 value of 0.22 and 101.5 μg/mL, respectively. The IC50 for antioxidantactivities of (1) and (2) were 2.83 and 13.95 μg/mL, respectively. The LC50 of (1) and (2) from BSLT were 350 and>1000 μg/mL, respectively.Identifikasi dan Studi Bioaktifitas Senyawa Flavonoid dari Macaranga hispida (Blume) Mull.Arg. Dua senyawaflavonoid, 5,7,3?,4?-tetrahidroksi-6-geranilflavonol (1) dan kaemferol 7-O-β-glukosa (2) telah diisolasi dari daunMacaranga hispida (Blume) Mull. Arg. Isolasi dan pemurnian dilakukan dengan metode kromatografi dan karakterisasistruktur kimia dilakukan dengan metode spektroskopi. 5,7,3', 4'-tetrahidroksi-6-geranil flavonol (1) kaemferol 7-Oglukosa(2) memiliki aktivitas sitotoksik sel murine leukemia P-388 dengan nilai IC50 masing-masing 0,22 dan 101,5μg/mL. Aktivitas antioksidan (1) dan (2) dinyatakan dengan nilai IC50 masing-masing sebesar 2,83 dan 13,95 μg/mL.Nilai LC50 dengan uji BSLT (1) dan (2) masing-masing 350 dan >1000 μg/mL."

"Determinasi Karbofuran pada Kondisi Kromatografi Cair Interaksi Hidrofilik menggunakan TSKgel®Amide-80 sebagai Fase Diam. Kromatografi cair interaksi hidrofilik (KCIH) digunakan dengan memanfaatkan kolom kapiler yang ramah lingkungan dalam rangka mempelajari perilaku retensi karbofuran. Perilaku retensi karbofuran diidentifikasi menggunakan beberapa jenis fase diam yang bersifat polar. Beberapa kondisi telah dilakukan untuk menyelidiki perilaku retensi karbofuran seperti studi perbandingan kolom TSKgel®Amide-80 dengan kolom polar lainnya, perbandingan perilaku retensi studi karbofuran pada berbagai panjang gelombang, efek air dalam mode KCIH, pengaruh konsentrasi buffer pada mode KCIH, dan kinerja analitik. Hasil penelitian menunjukkan bahwa TSKgel®Amide-80 lebih baik dibandingkan dengan fase diam polar lain dalam penentuan karbofuran. Selain itu panjang gelombang 251 dan 254 nm menghasilkan absorbansi lebih tinggi untuk karbofuran daripada yang lain. Sebagai tambahan, peningkatan kadar air dan konsentrasi garam penyangga pada fase gerak menyebabkan waktu retensi lebih cepat. Nilai perolehan kembali metode ini adalah 101 ± 10,1, sedangkan limit deteksi dan limit quantifikasi berturut-turut diperoleh sebesar 0,66 ppm dan 2,22 ppm. Disimpulkan bahwa TSKgel®Amide-80 memberikan hasil yang baik dalam penetapan karbofuran meskipun digunakan kromatografi cair kapiler dengan panjang kolom 10 cm.

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Hydrophilic interaction liquid chromatography (HILIC) equipped with an environmentally friendly capillary column was employed to investigate the retention behavior of carbofuran; a polar stationary phase was used as well. Several conditions were conducted to investigate the retention behavior of carbofuran, such as a comparison study TSKgel®Amide-80 with another polar column, a comparison study retention behavior of carbofuran on various wavelengths, the water content effect on HILIC mode, the effect of buffer concentration on HILIC mode, and the analytical performance of carbofuran. The results showed that TSKgel®Amide-80 exhibited a better performance than other polar stationary phases in carbofuran determination, and observations at wavelengths of 251 and 254 nm showed higher absorbance for carbofuran than others. In addition, the increase of water content and salt buffer concentration in the mobile phase led to a shorter retention time. The recovery of this method was 101 ± 10.1%, while the limit of detection and the limit of quantification were 0.66 ppm and 2.22 ppm, respectively. Consequently, TSKgel®Amide-80 offers a good performance in carbofuran determination, even with the application of 10 cm length column capillary liquid chromatography."

"Chlorella pyrenoidosa (C. pyrenoidosa) contains Chlorella Growth Factor (CGF), which consists of protein and polysaccharides. CGF is located inside the nucleus of cells and is beneficial to humans as a food supplement, an immunity booster, and an antioxidant. CGF formation of C. pyrenoidosa is influenced by medium composition. C. pyrenoidosa INK was cultured in a modified basal medium (MBM) with various concentrations of Mg2+ (0.5, 1.0, and 1.5 g/L) and Fe2+ (3.5×10-4 and 5.0×10-4 g/L). The experiments were run and analyzed under a completely randomized design using a 2-L bottle with three replications.The results showed that MBM with 1.0 g/L of Mg2+ and 3.5×10-4 g/L of Fe2+ yielded the optimal growth curve for C. pyrenoidosa. Analysis of protein content was carried out using the Lowry method with a spectrophotometer at λ=750 nm, and the obtained results were 0.0974 mg/mL (extract) and 6.4097 mg/ml (supernatant). Furthermore, analysis of glucose content was carried out using the phenol sulfate method (λ = 490 nm), and the obtained results were 49.331 ppm (extract) and 1566.911 ppm (supernatant). Analysis of amino acids in CGF using liquid chromatography-mass spectrometry (LC-MS) indicated the presence of tyrosine, proline, glutamate, alanine, valine, tryptopan, phenylalanine, methionine, and leucine-isoleucine.

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Pengaruh Konsentrasi Mg2+ dan Fe2+ dalam Media Kultur terhadap Pembentukan CGF oleh Mikroalga Chlorella pyrenoidosa INK dan Analisis Asam Amino dengan Kromatografi Cair-Spektrofotometri Massa. Chlorella pyrenoidosa (C. pyrenoidosa ) mengandung Chlorella Growth Factor (CGF), yang terdiri dari protein dan polisakarida. CGF terletak di dalam inti sel dan bermanfaat bagi manusia sebagai suplemen makanan, booster imunitas, dan antioksidan. Pembentukan CGF oleh C. pyrenoidosa dipengaruhi oleh komposisi medium. C. pyrenoidosa INK dikultur dalam media basal dimodifikasi (MBM) dengan berbagai konsentrasi Mg2+ (0,5, 1,0, dan 1,5 g/L) dan Fe2+ (3,5×10-4 dan 5,0×10-4 g/L). Percobaan dilakukan menggunakan rancangan acak lengkap dalam botol 2L dengan tiga kali pengulangan.Hasil penelitian menunjukkan bahwa MBM mengandung Mg2+ 1.0 g/L dan Fe2+ 3.5×10-4 g/L menghasilkan kurva pertumbuhan C. pyrenoidosa yang optimal. Analisis kandungan protein dilakukan dengan metode Lowry menggunakan spektrofotometer pada λ=750 nm, menghasilkan 0,0974 mg/mL (ekstrak) dan 6,4097 mg/mL (supernatan). Selanjutnya, analisis kadar glukosa dilakukan dengan metode fenol sulfat (λ=490 nm), hasil yang diperoleh 49,331 ppm (ekstrak) dan 1566,911 ppm (supernatan). Analisis asam amino dalam CGF menggunakan spektrometri massa kromatografi cair (KC-SM) menunjukkan adanya tirosin, prolin, asam glutamat, alanin, valin, triptopan, fenilalanin, metionin, dan leusin-isoleusin."

"ABSTRAKThe photocatalytic decolorization of real textile wastewater using pine wood (PW), bamboo (BB) and coconut shell (CS) charcoals TiO2-coated under UV irradiation were investigated. Biomass charcoals TiO2-coated were synthesized by the sol-gel and dip-coating technique. The structure features of biomass charcoals TiO2-coated were investigated by X-ray diffractometer (XRD) and scanning electron microscopy (SEM). our finding indicated that XRD data characteristic anatase phase reflections and SEM showed that TiO2 thin films distributed in the pores and cover on biomass charcoals. BB-TiO2 and CS- TiO2 showed high covering films of TiO2 on surface and filled full in the small pores but PW- TiO2 still had many large pores. decolorization of real textile wastewater using photocatalytic process was measured by Space Unit Method; S.U. with UV-VIS spectrophotometer. the photocatalytic tests indicated that decolorization of biomass-TiO2 were CS-TiO2, BB-TiO2 and PW-TiO2, respectively. details of the synthesis of biomass charcoals TiO2-coated and results of the characterization and decolorization studies are presented in this paper."

"ABSTRAKStudi terhadap penghalusan butir terus dikembangkan untuk mendapatkan sifat mekanis yang lebih baik pada baja karbon rendah. Slab baja karbon rendah berbentuk tangga dideformasi dengan metode warm rolling dengan temperature 500 0C, 550 0C, dan 600 0C untuk mendapatkan butir halus. Slab baja karbon rendah berbentuk tangga dideformasi sebesar 50 %, 66,67 %, 75 %, dan 80% di setiap temperatur, kemudian didinginkan dengan air. Rekristalisasi dinamis terjadi pada temperatur warm working di penelitian ini. Pengujian kekerasan dan hydrogen charging test dilakukan. Ketahanan baja karbon rendah terhadap serangan hidrogen dapat ditingkatkan dengan penghalusan butir ferit. Besar butir yang dihasilkan dari warm rolling mempengaruhi kekerasan dan ketahanannya terhadap serangan hidrogen.

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ABSTRACTStudiy of grain refinement have been developed to obtain better mechanical properties in low carbon steel. Wedge Shaped low carbon steel slabs were deformed with warm rolling method at temperature 500 0C, 550 0C, and 600 0C to obtain the refine grains. Wedge Shaped low carbon steel slabs were deformed with degree of deformation 50 %, 66,67 %, 75 %, and 80%. Dynamic recrystallization was confirmed at warm working temperature in this study. Hardness and hydrogen charging test had been done. Low carbon steel resistance to hydrogen attack can be improved with grain refinement. Grain size which been resulted from warm rolling process has an effect to hardness and hydrogen attack resistance."