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Abstrak :
Proses penyisihan senyawa fenol, COD dan 1,1,2,2-tetrakloroetana menggunakan teknik ozonasi katalitik dengan katalis Granular Activated Carbon (GAC) yang dikombinasikan dengan emisi sinar UV dilakukan dalam penelitian ini. Tujuan dari penelitian ini untuk memperoleh efektivitas aplikasi teknik ozonasi katalitik menggunakan sistem konfigurasi, yaitu: Ozon/GAC dan Ozon/UV/GAC dalam penyisihan limbah fenol, COD dan 1,1,2,2-tetrakloroetana dengan waktu sirkulasi (0, 15, 30, 45, 60, dan 120 menit). Limbah cair yang digunakan berasal dari limbah cair Laboratorium Industri Polyester di daerah Bogor. Analisis yang dilakukan meliputi analisis COD dengan metode FAS, analisis Fenol dengan menggunakan metode aminoantipirin dan analisis 1,1,2,2-tetrakloroetana dengan metode GC-FID. Setelah dilakukan penelitian, diketahui bahwa konfigurasi Ozon/UV/GAC dengan konsentrasi awal fenol 58,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 32,96 mg/L menghasilkan persentase penyisihan senyawa fenol 57,76%, COD 66,67% dan 1,1,2,2-tetrakloroetana 98,74% sedangkan konfigurasi Ozon/GAC dengan konsentrasi awal fenol 55,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 37,70 mg/L menghasilkan persentase penyisihan senyawa fenol 50,91%, COD 55,56% dan 1,1,2,2-tetrakloroetana 100%.

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Process eliminating compounds of phenol, COD and 1,1,2,2-tetrachloroethane using catalytic ozonation technique with catalyst Granular Activated Carbon (GAC) combination with UV light emission performed in this study. The purpose of this study was to obtain the effectiveness of applications catalytic ozonation technique using system configuration Ozone/GAC and Ozone/UV/GAC for eliminating in waste phenol, and 1,1,2,2-tetrachloroethane COD with circulation time (0, 15, 30, 45, 60, and 120 minutes). The wastewater was derived from wastewater Laboratory of Polyester Industrial in Bogor. The results were analyzed which comprising of COD with FAS method, phenol using aminoantipirin method and 1,1,2,2-tetrachloroethane with GC-FID method. The result of study shown that the configuration of the Ozone/ UV/GAC with an initial concentration of phenol 58,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 32,96 mg/L resulted in the percentage of eliminating phenol 57,76%, 66,67% COD and 1,1,2,2-tetrachloroethane 98,74% while the configuration of Ozone/GAC with an initial concentration of phenol 55,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 37,70 mg/L resulted in percentage of eliminating phenol 50,91%, 55,56% COD and 1,1,2,2-tetrachloroethane 100%.

Abstrak :

Perkembangan industri tekstil di Indonesia semakin pesat seiring dengan peningkatan ekspor produk berupa karya, serat, serta benang dan membuat air limbah tekstil meningkat seiring dengan laju produksi yang bertambah. Secara umum, air limbah dapat diolah menggunakan pengolahan fisika, kimia, serta biologi konvensional. Namun, sebagian besar zat warna yang digunakan dan terbuang dalam air limbah tekstil tergolong ke dalam zat warna jenis azo-dye yang merupakan zat warna resisten dan sulit untuk didegradasi secara biologis. Dalam penelitian ini, Congo Red digunakan sebagai representatif efluen limbah tekstil potensial dengan kompleksitas tinggi. Untuk mengatasi keterbatasan konvensional, pengolahan air limbah akan dilakukan menggunakan mekanisme oksidasi lanjut (Hybrid Advanced Oxidation Process, Hybrid AOP) yang menggabungkan proses O3, UV, serta serbuk besi. Skema injeksi ozon divariasikan dalam tiga skema untuk menekan penggunaan listrik dan mengamati pengaruh skema ozon terhadap reaksi. Serbuk besi sebagai katalis merupakan limbah serbuk besi sisa dari kegiatan konstruksi. Dengan menggunakan katalis hasil daur ulang, kebutuhan biaya untuk pengolahan air dapat ditekan dengan maksimal. Berdasarkan hasil penelitian, diketahui bahwa proses penyisihan didominasi oleh proses O3. Penambahan serbukl besi dalam eksperimen ini tidak menunjukkan peningkatan efisiensi yang signifikan. Selain itu, penambahan Fe juga memerlukan proses pemisahan besi yang menjadi kekurangan tersendiri. Penyishan warna paling tinggi diperoleh pada proses O3/UV dan O3 60 ON dengan pH 10,5 (97%). Walau begitu, penambahan UV dan mekanisme skematik pada proses O3 dapat berkontribusi dalam meningkatkan angka penyishan COD yang lebih baik. Lalu, penambahan serbuk besi meunjukan perbedaan yang tidak signifikan pada penyisihan.

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The growth in the Indonesian textile industry has gone rapidly along with the rise of textile product exporting. This has resulted in the increasing amount of waste water to treat. Generally, waste water could be treated using physics, chemistry, and conventional biology technology. Unfortunately, waste water from textile production contains resistant dyes that mainly belong to the family of azo-dye, which is hard to degrade. In this research, Congo Red was used as a representative for waste water from textile production that has high complexity. To solve the conventional treatment’s weakness, the waste water is treated using the Hybrid Advanced Oxidation (Hybrid AOP) process, which combines O3, UV, and Fe catalystsinto one proc ess. The injection scheme is variated to observe the impact of schematic ozonation in the reaction process. The Fe catalyst is powder waste from the construction site. The reuse scheme could reduce the cost needed to process wastewater. Based on the research, the dominant process in this combination is the O3 process. The addition of Fe catalysts does not significantly contribute to removal efficiency. Another drawback of adding a Fe catalyst is the need for additional processes to separate Fe powder after the reaction. The highest colour removal was achieved by O3/UV and O3 process at 60 ON scheme with pH value 10,5 (97,00%). Nevertheless, coupling of ozone with photolysis could lead to better removal of COD. Meanwhile, adding rebar flake waste show negligible effect on removal.

Abstrak :
ABSTRACT
Penelitian ini menawarkan alternatif metode dalam penyisihan kandungan pencemar pada limbah cair rumah sakit dengan teknologi ozonasi katalitik menggunakan Zeolit Alam Lampung (ZAL) jenis klinoptilolit yang dikombinasikan dengan radiasi sinar UV. Penelitian ini dilakukan dengan memvariasikan waktu penyisihan (0, 15, 30, 60, dan 120 menit); dan sistem konfigurasi ozonasi dalam pengolahan limbah cair, yaitu: ozon tunggal, Ozon-UV, Ozon-ZAL, Ozon-UV-ZAL. Analisis yang dilakukan meliputi analisis COD dengan metode FAS, analisis NH3-N dengan metode Nessler, metode TPC untuk mengetahui jumlah Coliform, dan analisis antibiotik dengan menggunakan metode aminoantipirin. Hasil penelitian menunjukkan bahwa konfigurasi Ozon-UV-ZAL sebagai konfigurasi yang terbaik dari semua konfigurasi yang dirancang dengan efisiensi penurunan COD, NH3-N, E.coli, Coliform, dan antibiotik masing-masing sebesar 50%; 28,74%; 100%; 83,14%; dan 100%.

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ABSTRACT
This research attempts to proffer an alternative method to eliminate pollutants from hospital wastewater through catalytic ozonation technology using combination of ZAL and UV radiation. The research was conducted with various circulation of time (0, 15, 30, 60, and 120 minutes); and system configuration of ozonation in wastewater treatment (Ozone, Ozone-UV, Ozone-ZAL, and Ozone-UV-ZAL). The results were analyzed which comprising of COD by FAS method, NH3-N by Nessler Method, TPC method to determine the number of E.coli/coliform, and aminoantipyrine method to antibiotics (phenol derivatives). To sum up, this research pointed out that the configuration of Ozone-UV-ZAL became the best configuration to treat the hospital wastewater with efficiency of removal reached: 50%; 28.74%; 100%-83.14%; and 100%.

Abstrak :
Pada penelitian ini dilakukan studi kasus proses penyisihan fenol dalam limbah cair dengan teknik ozonasi katalitik menggunakan GAC dan ZAL dalam reaktor unggun diam berpemutar. Perbandingan efektivitas penggunaan katalis pada teknik ozonasi katalitik ditinjau dari kuantitas radikal hidroksil, persesntase penyisihan fenol, neraca massa ozon, perubahan pH, serta karakteristik dan kemampuan adsorpsi katalis. Hasil penelitian menunjukkan bahwa GAC lebih unggul dari ZAL dalam menyisihkan senyawa fenol di limbah cair, baik melalui proses adsorpsi tunggal maupun dengan teknik ozonasi katalitik. Pada kondisi operasi yang sama, GAC memiliki kemampuan adsorpsi fenol yang lebih baik (persentase penyisihan fenol 60,86% dengan tingkat adsorpsi 1,302 mg/g) dibandingkan dengan ZAL (persentase penyisihan fenol 15,47% dengan tingkat adsorpsi 0,287 mg/g). Dalam larutan limbah bersuasana basa (pH ≈ 10), kombinasi ozon dengan GAC mampu menyisihkan fenol sebesar 88,94% dibandingkan ozonasi katalitik menggunakan ZAL hanya mampu menyisihkan fenol sebesar 50,97%.

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In this research, a case study of elimination process of phenol compounds in waste water by catalytic ozonation using GAC and ZAL in rotating packed bed reactor was examined. The effectiveness comparison of catalysts which used in ozonation catalytic is evaluated from quantity of hydroxyl radicals, percentage of phenol degradation, the mass balance of ozone, pH changes, catalyst`s adsorption capacity, and the changes of catalyst characteristics. The results showed that GAC is better than ZAL to eliminate phenol compounds in waste water, either through a single adsorption process as well as catalytic ozonation technique. At the same operating conditions, GAC has better ability for phenol adsorption (percentage of phenol degradation about 60,86% with the rate of adsorption up to 1,302 mg/g) compared to ZAL (percentage of phenol degradation about 15,47% with the rate of adsorption 0,287 mg/g). In waste water with alkali solution (pH ≈ 10), combination of ozone with GAC capable to remove phenol by 88,94%, compared to use catalytic ozonation using ZAL that only capable to remove phenol by 50,97%.

Abstrak :
[ABSTRAK
Penelitian ini bertujuan untuk mengurangi polutan dalam perairan yang salah satunya disebabkan oleh limbah cair tekstil dengan menggunakan teknik ozonasi katalitik. Digunakan UV254nm dan katalis GAC (Granular Carbon Active) batok kelapa serta batu bara yang akan meningkatkan prosentase penyisihan fenol dan turunannya dalam limbah cair industri tekstil. Perlakuan terbaik untuk penggunaan GAC batok kelapa adalah konfigurasi ozon+GAC100+UV dengan prosentase penyisihan fenol sebesar 95,87%, TOC 29,49% (dari 50,53 mg/L menjadi 35,6 mg/L), dan penyisihan COD 59,46% sedangkan ozon+GAC100 lebih rendah dengan penyisihan fenol sebesar 78,07%, TOC 13,39%, dan COD 58,97%. Sedangkan perlakuan terbaik untuk penggunaan GAC batu bara adalah konfigurasi ozon+GACC50+UV dengan prosentase penyisihan fenol sebesar 88,56%, TOC 32,52% (dari 50,53 mg/L menjadi 34,1 mg/L), dan penyisihan COD 59,63% sedangkan ozon+GACC50 lebih rendah dengan penyisihan fenol sebesar 78,07%, TOC 19,06%, dan COD 57,89%.

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ABSTRACT
The research goal is decreasing water pollution using catalytic ozonation technique because of textile effluent. Adding UV254nm with GAC (Granular Carbon Active) coconut and charcoal in configuration will increase percentage phenol elimination and derivate in textile effluent which got sedimentation tank (active sludge treatment). The result for GAC coconut is ozon+GAC100+UV configuration with percentage phenol elimination 95,87%, TOC 29,49% (from 50,53 mg/L into 35,6 mg/L), and COD 59,46%. In other hand, ozon+GAC100 configuration lower than adding UV with percentage phenol elimination 78,07%, TOC 13,39%, and COD 58,97%. another GAC (charcoal) had a best result is ozon+GACC50+UV with percentage phenol elimination 88,56%, TOC 32,52% (from 50,53 mg/L into 34,1 mg/L), and COD 59,63%. In the fact, without adding UV, ozon+GACC50 has less percentage phenol elimination 78,07%, TOC 19,06%, dan COD 57,89%.;The research goal is decreasing water pollution using catalytic ozonation technique because of textile effluent. Adding UV254nm with GAC (Granular Carbon Active) coconut and charcoal in configuration will increase percentage phenol elimination and derivate in textile effluent which got sedimentation tank (active sludge treatment). The result for GAC coconut is ozon+GAC100+UV configuration with percentage phenol elimination 95,87%, TOC 29,49% (from 50,53 mg/L into 35,6 mg/L), and COD 59,46%. In other hand, ozon+GAC100 configuration lower than adding UV with percentage phenol elimination 78,07%, TOC 13,39%, and COD 58,97%. another GAC (charcoal) had a best result is ozon+GACC50+UV with percentage phenol elimination 88,56%, TOC 32,52% (from 50,53 mg/L into 34,1 mg/L), and COD 59,63%. In the fact, without adding UV, ozon+GACC50 has less percentage phenol elimination 78,07%, TOC 19,06%, dan COD 57,89%.;The research goal is decreasing water pollution using catalytic ozonation technique because of textile effluent. Adding UV254nm with GAC (Granular Carbon Active) coconut and charcoal in configuration will increase percentage phenol elimination and derivate in textile effluent which got sedimentation tank (active sludge treatment). The result for GAC coconut is ozon+GAC100+UV configuration with percentage phenol elimination 95,87%, TOC 29,49% (from 50,53 mg/L into 35,6 mg/L), and COD 59,46%. In other hand, ozon+GAC100 configuration lower than adding UV with percentage phenol elimination 78,07%, TOC 13,39%, and COD 58,97%. another GAC (charcoal) had a best result is ozon+GACC50+UV with percentage phenol elimination 88,56%, TOC 32,52% (from 50,53 mg/L into 34,1 mg/L), and COD 59,63%. In the fact, without adding UV, ozon+GACC50 has less percentage phenol elimination 78,07%, TOC 19,06%, dan COD 57,89%., The research goal is decreasing water pollution using catalytic ozonation technique because of textile effluent. Adding UV254nm with GAC (Granular Carbon Active) coconut and charcoal in configuration will increase percentage phenol elimination and derivate in textile effluent which got sedimentation tank (active sludge treatment). The result for GAC coconut is ozon+GAC100+UV configuration with percentage phenol elimination 95,87%, TOC 29,49% (from 50,53 mg/L into 35,6 mg/L), and COD 59,46%. In other hand, ozon+GAC100 configuration lower than adding UV with percentage phenol elimination 78,07%, TOC 13,39%, and COD 58,97%. another GAC (charcoal) had a best result is ozon+GACC50+UV with percentage phenol elimination 88,56%, TOC 32,52% (from 50,53 mg/L into 34,1 mg/L), and COD 59,63%. In the fact, without adding UV, ozon+GACC50 has less percentage phenol elimination 78,07%, TOC 19,06%, dan COD 57,89%.]

Abstrak :
Senyawa fenol merupakan polutan berbahaya karena sifatnya yang beracun, korosif, dan karsinogenik. Senyawa ini banyak ditemukan dalam limbah cair industri yang jika dibuang langsung ke lingkungan tanpa pengolahan terlebih dahulu dapat memberi dampak yang sangat buruk pada lingkungan, yaitu menghambat aktivitas biota akuatik dan dapat mengakibatkan gangguan kesehatan pada tubuh. Teknologi ozonasi merupakan teknologi yang ramah lingkungan dan efektif untuk pengolahan limbah cair karena karakteristik ozon yang akan terdekomposisi dalam air membentuk oksidator-oksidator kuat, seperti radikal hidroksil. Selain itu, dilakukan pengembangan dengan teknologi ozonasi katalitik untuk mempercepat dekomposisi ozon menjadi radikal hidroksil yang memaksimalkan degradasi fenol. Pada penelitian ini, digunakan katalis ferolit karena memiliki efektivitas katalitik yang baik serta ketersediaannya yang banyak. Tujuan dari penelitian ini adalah untuk untuk membandingkan efektivitas teknik ozonasi katalitik dengan teknik ozonasi tunggal untuk proses degradasi senyawa fenol dalam reaktor kolom gelembung. Variasi yang digunakan berupa laju alir udara (8, 10 , 12 L/menit) dan laju alir limbah (255, 405, 495 mL/menit) pada teknik ozonasi, serta variasi massa katalis (50, 100, 200 g) pada teknik ozonasi katalitik. Titik optimal didapatkan dengan persentase degradasi mencapai 99,48% dan penurunan COD sebesar 74,01% pada teknik ozonasi dengan kondisi operasi pH awal limbah 12, laju alir udara 10 L/menit, dan laju alir limbah 495 mL/menit. Adapun dengan penambahan 200 g katalis ferolit pada teknik ozonasi katalitik, diperoleh hasil persentase degradasi sebesar 99,12% dan penurunan COD sebesar 40,17%. Dengan demikian, kehadiran ferolit memengaruhi kinerja proses ozonasi dengan efektivitas yang lebih rendah dibandingkan dengan ozonasi non-katalitik. ......Phenol compound is dangerous pollutants due to its toxicity, corrosivity, and carcinogenic effects. This compound is found in industrial wastewater which has adverse effects on the environment if discharged directly without treatment, such as inhibits the activity of aquatic biota and cause health problems in the body. Ozonation technology is an environmentally friendly and effective technology for wastewater treatment due to ozone characteristics which decompose in water to form strong oxidizers, such as hydroxyl radicals. In addition, it is improved with catalytic ozonation technology to accelerate ozone decomposition into hydroxyl radicals which maximize phenol degradation. In this study, the catalyst used is ferrolite due to its good catalytic effectiveness and has large availability. This study aims to compare the effectiveness of catalytic ozonation technique with a single ozonation technique for the degradation of phenol compounds in bubble column reactors. Variations used in this study are air flow rate (8, 10, 12 L/min) and waste flow rate (255, 405, 495 mL/min) in the ozonation technique, as well as variations in catalyst mass (50, 100, 200 g) on catalytic ozonation technique. The optimal condition is obtained by degradation percentage reached 99,48% and COD reduction of 74,01% in ozonation technique evaluating with operating conditions of initial waste pH of 12, air flow rate of 10 L/min, and waste flow rate of 495 mL/min. As for the addition of 200 g ferrolite to catalytic ozonation technique, the results showed the degradation percentage of 99,12% and COD reduction was 40,17%. Thus, the presence of ferrolite affected ozonation process performance with a lower effectiveness compared to non-catalytic ozonation.